发明授权
- 专利标题: High density ethylene polymer and method for producing the same
- 专利标题(中): 高密度乙烯聚合物及其制备方法
-
申请号: US793046申请日: 1997-03-27
-
公开(公告)号: US5973083A公开(公告)日: 1999-10-26
- 发明人: Fumio Matsushita , Fumihiko Yamaguchi , Tsutomu Idehara
- 申请人: Fumio Matsushita , Fumihiko Yamaguchi , Tsutomu Idehara
- 申请人地址: JPX Osaka
- 专利权人: Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人: Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人地址: JPX Osaka
- 优先权: JPX6-215218 19940818
- 主分类号: C08F4/02
- IPC分类号: C08F4/02 ; C08F4/619 ; C08F4/6192 ; C08F4/642 ; C08F10/00 ; C08F10/02 ; C08F110/02 ; C08F210/16
摘要:
Disclosed is a high density ethylene polymer comprising a homopolymer of ethylene, or a copolymer of ethylene with at least one comonomer selected from an .alpha.-olefin, a cyclic olefin, and linear, branched and cyclic dienes, and having the following properties: (a) a density d (g/cm.sup.3) of from 0.951 to 0.980; (b) an M.sub.I (g/10 minutes) of more than 3 and not more than 100 (M.sub.I is the melt flow rate as measured at 190.degree. C. under a load of 2.16 kg); (c) the polymer satisfying: log a.sub.kI .gtoreq.-0.844 log M.sub.I +1.462 [M.sub.I is as defined above, and a.sub.kI is the Izod impact strength (kgf.multidot.cm/cm.sup.2)]; (d) the polymer satisfying: log M.sub.IR .gtoreq.-0.094 log M.sub.I +1.520 [M.sub.I is as defined above, and M.sub.IR is the H.sub.MI /M.sub.I ratio in which H.sub.MI (g/10 minutes) is the melt flow rate as measured at 190.degree. C. under a load of 21.6 kg and M.sub.I is as defined above]; and wherein (e) the d (g/cm.sup.3) and the M.sub.I (g/10 minutes) satisfy: d.gtoreq.-0.00873 log M.sub.I +0.972. The ethylene polymer has excellent mechanical properties and excellent moldability, and can be advantageously produced by use of a catalyst comprising (A) a specific transition metal compound containing, as a ligand, an unsubstituted or substituted indenyl group, or di or tri substituted cyclopentadienyl group; (B) an inorganic solid component comprising a particulate inorganic solid having OH groups on a surface thereof and, carried thereon, an organoaluminumoxy compound having an alkyl group; and (C) an organoaluminum compound.
公开/授权文献
信息查询