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US5977265A Method for preparing brominated polycarbonates, and products obtained thereby 失效
制备溴化聚碳酸酯的方法及由此获得的产物

Method for preparing brominated polycarbonates, and products obtained
thereby
摘要:
High flow brominated polycarbonates, useful as flame retardant additives for other polymers such as polyesters, are obtained by equilibration of a brominated aromatic polycarbonate such as a tetrabromobisphenol A homo- or copolycarbonate with a di- or polyhydroxy aromatic compound such as bisphenol A, or a diaryl carbonate, and an equilibration catalyst, under conditions such that the weight average molecular weight of the brominated polycarbonate is reduced by at least 35%. Preferred equilibration catalysts are Group I metal carboxylates, such as sodium stearate, and hexaalkylguanidinium salts.
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