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US5985463A Coating containing hydroxy containing acrylosilane polymer to improve mar and acid etch resistance 失效
含羟基的涂料含有丙烯酸硅烷聚合物以改善耐酸蚀性

Coating containing hydroxy containing acrylosilane polymer to improve
mar and acid etch resistance
摘要:
A coating composition particularly useful as a clear coating used over a pigmented base coat that has improved resistance to marring and to acid etching when exposed to natural weathering conditions containing 40-70% by weight of film forming binder and 30-60% by weight of a volatile liquid carrier for the binder; wherein the binder containsa. 50-90% by weight, based on the weight of the binder, of an acrylosilane polymer of polymerized monomers from the following group: an alkyl methacrylate, an alkyl acrylate, each having 1-12 carbon atoms in the alkyl group, cycloaliphatic alkyl methacrylate, cycloaliphatic alkyl acrylate, styrene or any mixture of these monomers; hydroxy containing monomers from the following group: hydroxy alkyl methacrylate, hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group, or any mixtures of these monomers; and a mono-ethylenically unsaturated silane monomer;and the polymer having a weight average molecular weight of 1,000-15,000 determined by gel permeation chromatography.b. 10-50% by weight, based on the weight of the binder of an organic polyisocyanate; andwherein the ratio of isocyanate groups of the organic polyisocyanate to hydroxy groups of the of the acrylosilane polymer is about 0.4:1 to 1.3:1.
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