公开(公告)号：US5985463A

公开(公告)日：1999-11-16

申请号：US103852

申请日：1998-06-24

申请人： Jun Lin ,  John David Nordstrom

发明人： Jun Lin ,  John David Nordstrom

IPC分类号： C08G18/62 ,  C09D125/14 ,  C09D133/06 ,  C09D143/04 ,  C09D175/04 ,  B32B9/04

CPC分类号： C09D175/04 ,  C08G18/6295 ,  Y10T428/31663

摘要： A coating composition particularly useful as a clear coating used over a pigmented base coat that has improved resistance to marring and to acid etching when exposed to natural weathering conditions containing 40-70% by weight of film forming binder and 30-60% by weight of a volatile liquid carrier for the binder; wherein the binder containsa. 50-90% by weight, based on the weight of the binder, of an acrylosilane polymer of polymerized monomers from the following group: an alkyl methacrylate, an alkyl acrylate, each having 1-12 carbon atoms in the alkyl group, cycloaliphatic alkyl methacrylate, cycloaliphatic alkyl acrylate, styrene or any mixture of these monomers; hydroxy containing monomers from the following group: hydroxy alkyl methacrylate, hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group, or any mixtures of these monomers; and a mono-ethylenically unsaturated silane monomer;and the polymer having a weight average molecular weight of 1,000-15,000 determined by gel permeation chromatography.b. 10-50% by weight, based on the weight of the binder of an organic polyisocyanate; andwherein the ratio of isocyanate groups of the organic polyisocyanate to hydroxy groups of the of the acrylosilane polymer is about 0.4:1 to 1.3:1.

摘要翻译： 特别适用于在着色底涂层上使用的透明涂层的涂料组合物，其在暴露于包含40-70重量％成膜粘合剂和30-60重量％成膜粘合剂的天然风化条件下具有改善的防污性和酸蚀刻时， 用于粘合剂的挥发性液体载体; 其中所述粘合剂含有。 50-90重量％，基于粘合剂的重量，来自下列基团的聚合单体的丙烯基硅烷聚合物：烷基中具有1-12个碳原子的甲基丙烯酸烷基酯，丙烯酸烷基酯，甲基丙烯酸脂环族烷基酯 ，脂环族丙烯酸烷基酯，苯乙烯或这些单体的任何混合物; 来自下列基团的含羟基的单体：甲基丙烯酸羟烷基酯，烷基中具有1-4个碳原子的羟基烷基丙烯酸酯，或这些单体的任何混合物; 和单烯属不饱和硅烷单体; 并且通过凝胶渗透色谱测定的重均分子量为1,000-15,000的聚合物。 b。 10-50重量％，基于有机多异氰酸酯的粘合剂的重量; 并且其中有机多异氰酸酯的异氰酸酯基与丙烯酸硅烷聚合物的羟基的比例为约0.4:1至1.3:1。

公开(公告)号：US06592944B1

公开(公告)日：2003-07-15

申请号：US09913223

申请日：2001-08-08

申请人： Peter William Uhlianuk ,  John David Nordstrom

发明人： Peter William Uhlianuk ,  John David Nordstrom

IPC分类号： B05D302

CPC分类号： C09D175/04 ,  C08G18/3851 ,  C08G18/4045 ,  C08G18/4261 ,  C08G18/4291 ,  C08G18/44 ,  C08G18/58 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/8064 ,  C09D175/06 ,  C08L2666/16

摘要： The present invention provides for an etch and mar resistant low VOC clear coating composition most suitable for use as a top clear coat in multi-layered OEM or refinish automotive coatings. The coating composition includes polyisocyanate, polyester polyol and melamine components, where more than half of total composition solids include the polyester polyol and melamine components. The polyisocyanate component includes an aliphatic polyisocyanate. The composition may be formulated as a two-pack or one-pack coating composition, wherein the isocyanate functionalities are blocked with a blocker such as a mono-alcohol.

摘要翻译： 本发明提供了最适合用作多层OEM或修补汽车涂料中的顶部透明涂层的耐腐蚀和耐腐蚀的低VOC透明涂层组合物。 涂料组合物包括多异氰酸酯，聚酯多元醇和三聚氰胺组分，其中总组合物固体的一半以上包括聚酯多元醇和三聚氰胺组分。 多异氰酸酯组分包括脂族多异氰酸酯。 组合物可以配制成双组分或单组分涂料组合物，其中异氰酸酯官能团被封闭剂例如单醇封闭。

公开(公告)号：US06428898B1

公开(公告)日：2002-08-06

申请号：US09582834

申请日：2000-06-30

申请人： Robert J. Barsotti ,  Isidor Hazan ,  John David Nordstrom

发明人： Robert J. Barsotti ,  Isidor Hazan ,  John David Nordstrom

IPC分类号： B32B904

CPC分类号： C08G18/792 ,  C08G18/3212 ,  C08G18/3893 ,  C08G18/4063 ,  C08G18/423 ,  C08G18/4261 ,  C08G18/4692 ,  C08G18/6295 ,  C08G18/718 ,  C08G2105/02 ,  C09D175/04 ,  Y10T428/31663 ,  C08L2666/16

摘要： The present invention is directed to low VOC curable coating compositions suitable for use in various mar and etch resistant coatings, such as in automotive coatings. The binder of the composition includes silicon/hydroxyl and cross-linking components. The silicon/hydroxyl component includes one or more reactive oligomers having linear or branched cycloaliphatic moiety and at least two functional groups with at least one being a silane or silicate group, the remaining being a hydroxyl group. Applicants have unexpectedly discovered that by including silane or silicate functionalities in these reactive oligomers, the solids level of the composition can be significantly increased at reduced composition viscosities. As a result, such high solids low VOC compositions can be readily applied by conventional application means, such as by spraying.

摘要翻译： 本发明涉及适合用于各种耐腐蚀和耐蚀刻涂层的低VOC可固化涂料组合物，例如在汽车涂料中。 组合物的粘合剂包括硅/羟基和交联组分。 硅/羟基组分包括一种或多种具有直链或支链脂环族部分的反应性低聚物和至少两个官能团，其中至少一个为硅烷或硅酸酯基团，其余为羟基。 申请人意外地发现通过在这些反应性低聚物中包括硅烷或硅酸盐官能团，组合物的固体含量可以以降低的组合物粘度显着增加。 结果，这种高固体含量的低VOC组合物可以通过常规的施用方法，例如通过喷雾而容易地施加。

公开(公告)号：US06426148B1

公开(公告)日：2002-07-30

申请号：US09462968

申请日：2000-01-14

申请人： Robert John Barsotti ,  Lee R. Harper ,  John David Nordstrom

发明人： Robert John Barsotti ,  Lee R. Harper ,  John David Nordstrom

IPC分类号： C09D17504

CPC分类号： C08G18/4294 ,  C08G18/4291 ,  C08G18/58 ,  C08G18/6229 ,  C08G18/792 ,  C09D175/04 ,  Y10T428/31551

摘要： A curable coating composition comprising, in an organic solvent, a binder of (i) a non-isocyanate oligomer or blend of oligomers containing at least two functional groups with at least one being an epoxy group, the remaining being epoxy or hydroxyl; (ii) optionally a polyester, oligoester, or acrylic polymer with at least two hydroxyl groups; and (iii) an oligomeric crosslinker or blend of crosslinkers which contain at least two isocyanate groups.

摘要翻译： 一种可固化涂料组合物，其在有机溶剂中包含（i）非异氰酸酯低聚物或含有至少两个官能团的低聚物共混物的粘合剂，至少一个为环氧基，其余为环氧基或羟基; （ii）任选具有至少两个羟基的聚酯，低聚酯或丙烯酸聚合物; 和（iii）含有至少两个异氰酸酯基的交联剂或交联剂的混合物。

公开(公告)号：US5641574A

公开(公告)日：1997-06-24

申请号：US553399

申请日：1995-11-21

申请人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

发明人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

IPC分类号： B05D1/36 ,  B05D7/00 ,  B05D7/24 ,  C08G59/42 ,  C09D157/00 ,  C09D163/00 ,  C09D167/00 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C09D201/00

CPC分类号： B05D7/532 ,  C08G59/42 ,  Y10T428/31511

摘要： A process for forming an overcoat by the two-coat one-bake method wherein a base coat composition and a clear coat composition are applied to a substrate ##STR1## wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is an aqueous coating composition consisting primarily of: (I) an aqueous dispersion or solution of a polymer containing a crosslinkable functional group, (II) a crosslinking agent, (III) a coloring pigment, and (IV) water, the clear coat composition being a coating composition comprising: (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof, (B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by formula (1) wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500, and (C) a curing catalyst.

摘要翻译： PCT No.PCT / JP93 / 00678 Sec。 371日期：1995年11月21日 102（e）1995年11月21日日期PCT提交1993年5月24日PCT公布。 第WO94 / 27741号公报 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法，其中将底涂层组合物和透明涂层组合物施加到基底上（1）湿润湿润，然后在 该方法的特征在于底涂层组合物是主要由以下组成的水性涂料组合物：（I）含有可交联官能团的聚合物的水性分散体或溶液，（II）交联剂，（ III）着色颜料和（IV）水，所述透明涂料组合物为涂料组合物，其包含：（A）至少一种选自以下的树脂：（i）具有至少一个环氧基的树脂和至少一种 （ii）分子中具有至少两个环氧基的树脂（ii-1）和（ii-2）分子中具有至少两个羟基的树脂的树脂混合物，（iii）分子中具有至少两个羟基的树脂， 分子中具有至少两个环氧基的树脂，和（iv）任何混合物 （B）交联剂，其包含具有至少两个非环状酸酐基团并由式（1）表示的化合物，其中R是具有2至50个碳原子的一价烃基，R'是具有2至 50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n为1〜500的整数，（C）固化催化剂。