发明授权
US06001766A Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes 失效
用石蜡溶解的烷基铝氧烷活化的乙烯聚合反应的双金属催化剂

Bimetallic catalysts for ethylene polymerization reactions activated
with paraffin-soluble alkylalumoxanes
摘要:
Catalyst compositions for homopolymerization and copolymerization of ethylene which comprise two transition metal compounds, one of them a cyclopentadienyl complex of a transition metal and another a non-metallocene derivative of a transition metal are described. The catalysts are activated by alkylalumoxanes that are soluble in non-aromatic hydrocarbons. Bimetallic catalysts of this invention are suitable for the manufacture of ethylene homopolymers and copolymers with broad bimodal molecular weight distributions. The alkyl alumoxanes have at least one [AR(R)--O--] repeating group in which R is an alkyl group of at least two carbon atoms.
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