发明授权
US06001766A Bimetallic catalysts for ethylene polymerization reactions activated
with paraffin-soluble alkylalumoxanes
失效
用石蜡溶解的烷基铝氧烷活化的乙烯聚合反应的双金属催化剂
- 专利标题: Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
- 专利标题(中): 用石蜡溶解的烷基铝氧烷活化的乙烯聚合反应的双金属催化剂
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申请号: US998146申请日: 1997-12-24
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公开(公告)号: US06001766A公开(公告)日: 1999-12-14
- 发明人: Yury V. Kissin , Robert I. Mink , Thomas E. Nowlin
- 申请人: Yury V. Kissin , Robert I. Mink , Thomas E. Nowlin
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: B01J31/14
- IPC分类号: B01J31/14 ; B01J31/22 ; C08F4/02 ; C08F4/60 ; C08F4/658 ; C08F4/659 ; C08F4/6592 ; C08F10/02 ; C08F210/16 ; B01J31/00 ; B01J37/00
摘要:
Catalyst compositions for homopolymerization and copolymerization of ethylene which comprise two transition metal compounds, one of them a cyclopentadienyl complex of a transition metal and another a non-metallocene derivative of a transition metal are described. The catalysts are activated by alkylalumoxanes that are soluble in non-aromatic hydrocarbons. Bimetallic catalysts of this invention are suitable for the manufacture of ethylene homopolymers and copolymers with broad bimodal molecular weight distributions. The alkyl alumoxanes have at least one [AR(R)--O--] repeating group in which R is an alkyl group of at least two carbon atoms.
公开/授权文献
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