A lithographic imaging member has a support having thereon a melanophobic silicone copolymer layer and a contiguous surface melanophilic layer composed of an inorganic or organic polymeric matrix. Either or both layers includes a photothermal conversion material capable of converting irradiation, such as IR radiation, to heat in exposed regions. The imaging member can include in one or more layers a material capable of promoting adhesion across the interface of the contiguous layers. This imaging member can be digitally imaged, for example using a laser, and used for printing without wet processing.