A temple structure of the eyeglasses includes a chamber defined in the end thereof which is pivotally connected to the front of the eyeglasses, a transparent portion is defined in the outside of the temple so as to see the interior of the chamber. A perfume tube is received in the chamber and has a valve device attached thereto which has an operation end extending from the end of the temple so that when pivoting the temple toward the front, the operation end is pushed and the perfume is dispensed from the outlet defined in the operation end.