发明授权
US6093766A Process for preparing polyvinyl alcohol stabilized solvent- and plastifier-free polyvinyl ester dispersions 失效
制备聚乙烯醇稳定的无溶剂和无增塑剂的聚乙烯酯分散体的方法

  • 专利标题: Process for preparing polyvinyl alcohol stabilized solvent- and plastifier-free polyvinyl ester dispersions
  • 专利标题(中): 制备聚乙烯醇稳定的无溶剂和无增塑剂的聚乙烯酯分散体的方法
  • 申请号: US150594
    申请日: 1998-09-10
  • 公开(公告)号: US6093766A
    公开(公告)日: 2000-07-25
  • 发明人: Martin JakobWerner Prass
  • 申请人: Martin JakobWerner Prass
  • 申请人地址: DEX Frankfurt
  • 专利权人: Clariant GmbH
  • 当前专利权人: Clariant GmbH
  • 当前专利权人地址: DEX Frankfurt
  • 优先权: DEX19739936 19970911
  • 主分类号: C08F263/02
  • IPC分类号: C08F263/02 C08J3/09 C08L31/04
Process for preparing polyvinyl alcohol stabilized solvent- and
plastifier-free polyvinyl ester dispersions
摘要:
The present invention relates to the preparation of heterogeneous, water-resistant polyvinyl ester dispersions having a film-forming temperature of below 10.degree. C., comprising the formation of a homo- or copolymer A, having a glass transistion temperature of more that 20.degree. C., by seed polymerization of a monomer mixture comprising 85-100% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms,0-10% by weight of an .alpha.,.beta.-unsaturated carboxylic acid and/or of an N-functional compound and0-5% by weight of a polyethylenically unsaturated monomer in the presence of a seed base comprising a copolymer B having a glass transition temperature of below 20.degree. C., comprising45-98% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms,2-50% by weight of an .alpha.-olefin having 1 to 4 carbon atoms and0-5% by weight of a polyethylenically unsaturated monomer.
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