发明授权
US6136894A Aqueous epoxy resin system with curing agent from reacting
acid-terminated polyalkylene glycol with epoxy-amine adduct
有权
具有固化剂的水性环氧树脂体系,由酸封端的聚亚烷基二醇与环氧胺加合物反应
- 专利标题: Aqueous epoxy resin system with curing agent from reacting acid-terminated polyalkylene glycol with epoxy-amine adduct
- 专利标题(中): 具有固化剂的水性环氧树脂体系,由酸封端的聚亚烷基二醇与环氧胺加合物反应
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申请号: US443871申请日: 1999-11-19
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公开(公告)号: US6136894A公开(公告)日: 2000-10-24
- 发明人: Charles J. Stark, deceased , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
- 申请人: Charles J. Stark, deceased , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
- 申请人地址: TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: TX Houston
- 主分类号: C08G59/44
- IPC分类号: C08G59/44 ; C08G59/18 ; C08G59/50 ; C08G59/62 ; C08L63/00 ; C09D163/00 ; C08G59/14 ; C08K3/20 ; C08L63/02
摘要:
An aqueous epoxy resin system suitable for coatings comprises (a) water, (b) at least one epoxy resin and (c) a curing agent prepared by (i) reacting at least one polyamine having at least 3 active amine hydrogen atoms per molecule and at least one epoxy resin in an epoxy equivalent to to polyamine mole ratio of from 0.9:1 to 1:10 to obtain an amine-terminated intermediate; (ii) reacting the amine-terminated intermediate with from 0.5 to 25 weight percent, based on the amine-terminated intermediate, of an acid-terminated polyalkylene glycol to yield an amine-terminated curing agent. The amine-terminated intermediate can be capped with a monoepoxide in an amine hydrogen to epoxy groups ratio of from about 1.5:1 to 30:1 prior to reaction with the acid-terminated polyalkylene glycol, or the amine-terminated curing agent following step (ii) can be capped with a monoepoxide in an amine hydrogen atoms to epoxy groups ratio of from about 2:1 to 30:1.
公开/授权文献
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