发明授权
US6136894A Aqueous epoxy resin system with curing agent from reacting acid-terminated polyalkylene glycol with epoxy-amine adduct 有权
具有固化剂的水性环氧树脂体系,由酸封端的聚亚烷基二醇与环氧胺加合物反应

Aqueous epoxy resin system with curing agent from reacting
acid-terminated polyalkylene glycol with epoxy-amine adduct
摘要:
An aqueous epoxy resin system suitable for coatings comprises (a) water, (b) at least one epoxy resin and (c) a curing agent prepared by (i) reacting at least one polyamine having at least 3 active amine hydrogen atoms per molecule and at least one epoxy resin in an epoxy equivalent to to polyamine mole ratio of from 0.9:1 to 1:10 to obtain an amine-terminated intermediate; (ii) reacting the amine-terminated intermediate with from 0.5 to 25 weight percent, based on the amine-terminated intermediate, of an acid-terminated polyalkylene glycol to yield an amine-terminated curing agent. The amine-terminated intermediate can be capped with a monoepoxide in an amine hydrogen to epoxy groups ratio of from about 1.5:1 to 30:1 prior to reaction with the acid-terminated polyalkylene glycol, or the amine-terminated curing agent following step (ii) can be capped with a monoepoxide in an amine hydrogen atoms to epoxy groups ratio of from about 2:1 to 30:1.
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