发明授权
US6136936A Ethylene copolymers, process for the preparation of ethylene-based polymers and catalyst system used therein 失效
乙烯共聚物,用于制备乙烯基聚合物的方法和其中使用的催化剂体系

Ethylene copolymers, process for the preparation of ethylene-based
polymers and catalyst system used therein
摘要:
Ethylene copolymers are prepared with comonomers selected from:(a) .alpha.-olefins,(b) cycloolefins and(c) polyenes,with a content of ethylene units of between 80 and 99 mol %, a content of units derived from .alpha.-olefin, cycloolefin and/or polyene comonomers of between 1 and 20 mol %, characterized in that:(a) in TREF (Temperature Rising Elution Fractionation) analysis, a quantity equal to at least 90% by weight of the copolymer is eluted within a temperature interval of less than 50.degree. C., and(b) M.sub.w /M.sub.n >3, where M.sub.w is the weight-average molecular weight and M.sub.n is the number-average molecular weight, both determined by means of GPC.
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