发明授权
US6147247A Process for simultaneously preparing 6-aminocapronitrile and
hexamethylene diamine
有权
同时制备6-氨基己腈和六亚甲基二胺的方法
- 专利标题： Process for simultaneously preparing 6-aminocapronitrile and hexamethylene diamine
- 专利标题（中）： 同时制备6-氨基己腈和六亚甲基二胺的方法
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申请号： US254454申请日： 1999-03-10
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公开(公告)号： US6147247A公开(公告)日： 2000-11-14
- 发明人: Guido Voit , Klemens Flick , Hermann Luyken , Alwan Rehfinger , Peter Bassler
- 申请人： Guido Voit , Klemens Flick , Hermann Luyken , Alwan Rehfinger , Peter Bassler
- 申请人地址： DEX Ludwigshafen
- 专利权人： BASF Aktiengesellschaft
- 当前专利权人： BASF Aktiengesellschaft
- 当前专利权人地址： DEX Ludwigshafen
- 优先权： DEX19636765 19960910
- 主分类号： B01J23/78
- IPC分类号： B01J23/78 ; C07B61/00 ; C07C209/48 ; C07C211/12 ; C07C253/30 ; C07C255/24 ; C07C255/03
摘要：
A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from a mixture comprising a phosphorus-containing compound and essentially adiponitrile and obtained by reaction of butadiene with hydrocyanic acid in the presence of a catalyst comprising a phosphorus-containing compound comprises(1) reducing the weight proportion of phosphorus-containing compound, calculated as phosphorus, in the mixture,(2) partially hydrogenating the resulting mixture in the presence of a catalyst to form an .alpha.,.omega.-aminonitrile, and(3) removing 6-aminocapronitrile and hexamethylenediamine from the mixture.
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