发明授权
- 专利标题: Process for the preparation of pesticides
- 专利标题(中): 农药制备工艺
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申请号: US762217申请日: 1996-12-06
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公开(公告)号: US6156923A公开(公告)日: 2000-12-05
- 发明人: Saleem Farooq , Stephan Trah , Hugo Ziegler , Rene Zurfluh
- 申请人: Saleem Farooq , Stephan Trah , Hugo Ziegler , Rene Zurfluh
- 申请人地址: NJ Summit
- 专利权人: Novartis Corporation
- 当前专利权人: Novartis Corporation
- 当前专利权人地址: NJ Summit
- 优先权: CHX3464/95 19951207
- 主分类号: C07C249/04
- IPC分类号: C07C249/04 ; C07C249/12 ; C07C251/48 ; C07C251/60
摘要:
The invention relates to a process for the preparation of compounds of the formula ##STR1## or, if appropriate, a tautomer thereof, in each case in the free form or in salt form, in whichA, X, Y, Z, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.7, R.sub.9 and n are as defined in claim 1 and the C.dbd.N double bond marked with E has the E configuration, which comprisesa1) reacting either a compound of the formula (II) mentioned above with a compound of the formula (III) mentioned above, in which X.sub.1 is a leaving group, ora2) a compound of the formula (IV) mentioned above, if appropriate in the presence of a base, with a compound of the formula (V) mentioned above, orb1) reacting a compound of the formula (VI) mentioned above with a compound of the formula R.sub.7 --A--X.sub.2 (VII), in which X.sub.2 is a leaving group, and either further reacting the compound thus obtainable, of the formula (IV), for example according to method a2), orb2) reacting it with hydroxylamine or a salt thereof, if appropriate in the presence of a basic or acid catalyst, and further reacting the compound thus obtainable, of the formula (II), for example according to method a1), orc) reacting a compound of the formula (VII), mentioned above with a C.sub.1 -C.sub.6 alkyl nitrite and further reacting the compound thus obtainable, of the formula (VI), for example according to method b), the E isomers of the compounds of the formulae (II), (IV) and (VI), a process for their preparation and their use for the preparation of compounds of the formula (I).
公开/授权文献
- USD341040S School desk 公开/授权日:1993-11-09