发明授权
US6166125A Graded-refractive-index optical plastic material and method for its production 有权
渐变折射率光学塑料材料及其制造方法

Graded-refractive-index optical plastic material and method for its
production
摘要:
A graded-refractive-index optical plastic material comprising an amorphous fluorine-containing polymer (A) having substantially no C--H bond, and at least one fluorine-containing polycyclic compound (B) having a refractive index higher by at least 0.005 than the fluorine-containing polymer (A), wherein the fluorine-containing polycyclic compound (B) is distributed in the fluorine-containing polymer (A) with a concentration gradient such that the concentration decreases in a direction of from the center to the periphery, and the fluorine-containing polycyclic compound (B) is at least one fluorine-containing polycyclic compound selected from the group consisting of the following compounds (B1), (B2) and (B3):(B1) a fluorine-containing non-condensed polycyclic compound having at least two fluorine-containing rings bonded by a bond containing at least one member selected from the group consisting of a triazine ring, an oxygen atom, a sulfur atom, a phosphorus atom and a metal atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring and having a fluorine atom or a perfluoroalkyl group, said polycyclic compound having substantially no C--H bond;(B2) a fluorine-containing non-condensed polycyclic compound having at least three fluorine-containing rings bonded directly or by a bond containing a carbon atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring and having a fluorine atom or a perfluoroalkyl group, said polycyclic compound having substantially no C--H bond;(B3) a fluorine-containing condensed polycyclic compound which is a condensed polycyclic compound composed of at least three carbon rings or heterocyclic rings, and which has substantially no C--H bond.
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