发明授权
- 专利标题: Preparation of olefins
- 专利标题(中): 烯烃的制备
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申请号: US275784申请日: 1999-03-25
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公开(公告)号: US6166279A公开(公告)日: 2000-12-26
- 发明人: Peter Schwab , Ralf Schulz , Michael Schulz , Boris Breitscheidel , Gerald Meyer
- 申请人: Peter Schwab , Ralf Schulz , Michael Schulz , Boris Breitscheidel , Gerald Meyer
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX19813720 19980327
- 主分类号: B01J23/36
- IPC分类号: B01J23/36 ; C07B61/00 ; C07C6/02 ; C07C7/163 ; C07C11/06 ; C07C41/06 ; C10G35/06 ; C07C1/00 ; C07C6/00
摘要:
The preparation of olefins from steam cracker or refinery C.sub.4 streams is carried out by selective hydrogenation of butadienes and acetylenic impurities in the steam cracker or refinery C.sub.4 stream, with simultaneous or subsequent, at least partial isomerization of 1-butene to 2-butene, followed by removal of i-butene from the C.sub.4 stream by reaction with an alcohol to form an ether, followed by removal of oxygen-containing impurities from the C.sub.4 stream using adsorber materials, followed by two-stage metathesis of the butenes in the C.sub.4 stream by conversion of 1-butene and 2-butene present in the C.sub.4 stream into propene and 2-pentene and subsequent reaction of the 2-pentene with ethene in the presence of a metathesis catalyst to form propene and 1-butene. Optionally, butadiene may be removed from the C.sub.4 stream by extractive distillation in a preliminary step.
公开/授权文献
- US5476776A Immobilized enzymes for use in an electrochemical sensor 公开/授权日:1995-12-19
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