发明授权
- 专利标题: Catalyst mixture for ring-opening metathesis polymerization
- 专利标题(中): 用于开环易位聚合的催化剂混合物
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申请号: US08970989申请日: 1997-11-14
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公开(公告)号: US06171995B2公开(公告)日: 2001-01-09
- 发明人: Andreas M{umlaut over (u)}hlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
- 申请人: Andreas M{umlaut over (u)}hlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
- 优先权: CH2826/96 19961115
- 主分类号: B01J3100
- IPC分类号: B01J3100
摘要:
A composition, comprising (a) a compound of formula I (R1R2R3P)xLyM2+Z1−Z2− (I), wherein R1, R2 and R3 are each independently of one another H, C1-C20alkyl, C1-C20-alkoxy; C4-C12cycloalkyl which is unsubstituted or substituted by C1-C6-alkyl, C1-C6haloalkyl or C1-C6alkoxy; C4-C12cycloalkoxy which is unsubstituted or substituted by C1-C6-alkyl, C1-C6haloalkyl or C1-C6alkoxy; C6-C16aryl which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; C6-Cl6aryloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; C7-C16-aralkyloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; or C7-C16aralkyloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6-haloalkyl or C1-C6alkoxy; or R2 and R3 together are tetra- or pentamethylene which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; tetra- or pentamethylenedioxyl which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; tetra- or pentamethylene which is condensed with one or two 1,2-phenylene radicals and which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; tetra- or pentamethylenedioxyl which is condensed with one or two 1,2-phenylene radicals and which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; or tetramethylenedioxyl which is condensed in the 1,2- and 3,4-positions with 1,2-phenylene and which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; and R1 has the meaning cited above; L is a neutral ligand; M is Ru or Os; Z1− and Z2− are each a singly charged anion, or Z1− and Z2− together are a doubly charged anion; x is a number from 1 to 3, and y is a number from 0 to 3, wherein 2≦x+y ≦4; and (b) a compound of formula II R4—C≡C—H (II), wherein R4 is hydrogen or a monovalent organic radical of up to 30 carbon atoms which may contain one or several silicon, phosphorus, nitrogen, oxygen, sulfur or halogen atoms, is suitable as storage-stable two-component catalyst for the ring-opening metathesis polymerisation of cyclopentadiene adducts and makes it possible to polymerise dicyclopentadiene and other cydopentadiene adducts within a short time and with high enthalpy of reaction and only little weight loss.
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