A recording medium which includes a first substance and a second substance, wherein an external energy is applied to at least one of the first and second substances to react them in order to change the optical characteristics of the substances for recording information, the recording medium including: a first layer composed of a first substance including at least one of S and Se, a second layer composed of a second substance including a metal, and a barrier layer being disposed between the first and second layers, which allows the reaction between the first and second layers when laser beam for recording is irradiated as an external energy, and suppresses the reaction between the first and second layers when laser beam for recording is not irradiated. Alternatively, the recording medium can be free from the barrier layer, and the second substance can be arranged to have two or more compositionally different portions or two or more phases with a different crystalline state. Thus, when the external energy is not applied, the reaction between the first substance and the second substance is suppressed. Hence, the recording characteristics of the recording medium is inhibited from degrading.