发明授权
- 专利标题: Process for preparing mixtures of linear organopolysiloxanes
- 专利标题(中): 线性有机聚硅氧烷混合物的制备方法
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申请号: US09413123申请日: 1999-10-06
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公开(公告)号: US06232423B1公开(公告)日: 2001-05-15
- 发明人: Thomas Köhler , Manfred Meisenberger
- 申请人: Thomas Köhler , Manfred Meisenberger
- 优先权: DE19846397 19981008
- 主分类号: C08G7708
- IPC分类号: C08G7708
摘要:
Mixtures of linear organopolysiloxanes of the general formula 1 for R3SiO—(SiR2O)n—SiR3 (1) are produced by a process in which organochlorosilanes of the general formula 2 R4−ySiCly (2) where R is identical or different and is a hydrogen atom or an unsubstituted or substituted hydrocarbon radical having from 1 to 18 carbon atoms, Y is 1 or 2, and n is 0 or an integer from 1 to 50, are reacted continuously in a closed circulation system with water which may, if desired, have been acidified with hydrochloric acid, where the HCl concentration in the hydrochloric acid discharged is less than 25% by weight. Low molecular weight oligomer mixtures substantially free of both cyclic organosiloxanes and organosilicon compounds containing Si—Cl are economically produced.
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