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公开(公告)号：US08710254B2
公开(公告)日：2014-04-29
申请号：US13501962
申请日：2010-10-06
IPC分类号： C07F7/20
CPC分类号： C07F7/21 , C07F7/0874
摘要： Silsesquisiloxanes are produced in high yield and purity in a minimal number of process steps by reacting quaternary ammonium silicates with disiloxanes in a precipitant liquid which causes the silsesquisiloxane product to be precipitated in high purity.
摘要翻译： 在最少数量的工艺步骤中通过使硅酸季铵与二硅氧烷在沉淀剂液体中反应而使硅硅氧烷产物以高纯度沉淀出来，以高产率和纯度生产硅聚硅氧烷。
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公开(公告)号：US06350440B1
公开(公告)日：2002-02-26
申请号：US09374179
申请日：1999-08-13
IPC分类号： A61K748
CPC分类号： A61Q1/12 , A61K8/585 , A61Q15/00 , A61Q17/04 , A61Q19/10 , C07F7/0838 , C08B37/0084 , C08G77/045 , C08L83/04 , C08L83/00
摘要： The invention relates to mixtures of linear organosiloxanes of the general formula 1 R3SiO—(SiR2O)n—SiR3 (1), where R can be identical or different and is a hydrocarbon radical having from 1 to 18 carbon atoms which is optionally substituted by fluorine, chlorine or cyano radicals and is free from ethylenically or acetylenically unsaturated bonds, and n has values from 0 to 20, where the mean number of carbon atoms of the radicals R is at most 3 and where the mixtures have evaporated, measured in accordance with DIN 53249, to an extent of from 80 to 95% by weight after 30 minutes, to an extent of from 90 to 99% by weight after 60 minutes and to an extent of from 95 to 100% by weight after 120 minutes. The mixtures of linear organosiloxanes are added to cosmetic formulations.
摘要翻译： 本发明涉及通式1的线性有机硅氧烷的混合物，其中R可以相同或不同，是具有1至18个碳原子的烃基，其任选被氟，氯或氰基取代，并且不含烯属或炔属不饱和键 ，并且具有0至20的值，其中基团R的平均碳原子数最多为3，并且根据DIN 53249测量的混合物已蒸发至30至30重量％的程度 分钟，在60分钟后达到90至99重量％，在120分钟后达到95至100重量％。将线性有机硅氧烷的混合物加入到化妆品制剂中。
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公开(公告)号：US07666969B2
公开(公告)日：2010-02-23
申请号：US11746676
申请日：2007-05-10
CPC分类号： C08G77/12 , C08G77/06 , C08G77/20 , C09D183/04
摘要： One-component, H-siloxane-containing addition-crosslinkable silicone resins, are prepared by charging a reactor with water and a solvent mixture of at least one aromatic solvent and at least one alkyl ester, adding a chlorosilane mixture containing an Si—H functional silane and a silane bearing an unsaturated hydrosilylatable group with stirring, the temperature not being above 50° C., separating an aqueous phase comprising a one-component, H-siloxane-containing addition-crosslinkable silicone resin, and washing the phase comprising the one-component, H-siloxane-containing addition-crosslinkable silicone resin in at least two washing steps to reduce residual HCl content, a final washing carried out using a 0.01%-1.0% strength aqueous solution of a base with a pH between 7.00-8.50, at a temperature of 20-50° C.
摘要翻译： 通过向反应器中加入含有至少一种芳香族溶剂和至少一种烷基酯的溶剂混合物，加入含有Si-H官能团的氯代硅烷混合物来制备含单硅氧烷的可加成交联硅氧烷树脂 硅烷和含有不饱和可氢化甲硅烷基的基团的硅烷在搅拌下，温度不高于50℃，分离含有单组分的含H-硅氧烷的可加成交联的有机硅树脂的水相，并洗涤包含一个 - 组分，含H-硅氧烷的可加成交联的有机硅树脂，至少两个洗涤步骤以减少残留的HCl含量，最后的洗涤使用0.01％-1.0％强度的碱的水溶液进行，pH为7.00-8.50 ，温度为20-50℃
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公开(公告)号：US20070265410A1
公开(公告)日：2007-11-15
申请号：US11746676
申请日：2007-05-10
IPC分类号： C08G77/12
CPC分类号： C08G77/12 , C08G77/06 , C08G77/20 , C09D183/04
摘要： One-component, H-siloxane-containing addition-crosslinkable silicone resins, are prepared by charging a reactor with water and a solvent mixture of at least one aromatic solvent and at least one alkyl ester, adding a chlorosilane mixture containing an Si—H functional silane and a silane bearing an unsaturated hydrosilylatable group with stirring, the temperature not being above 50° C., separating an aqueous phase comprising a one-component, H-siloxane-containing addition-crosslinkable silicone resin, and washing the phase comprising the one-component, H-siloxane-containing addition-crosslinkable silicone resin in at least two washing steps to reduce residual HCl content, a final washing carried out using a 0.01%-1.0% strength aqueous solution of a base with a pH between 7.00-8.50, at a temperature of 20-50° C.
摘要翻译： 通过向反应器中加入含有至少一种芳香族溶剂和至少一种烷基酯的溶剂混合物，加入含有Si-H官能团的氯代硅烷混合物来制备含单硅氧烷的可加成交联硅氧烷树脂 硅烷和含有不饱和可氢化甲硅烷基的基团的硅烷在搅拌下，温度不高于50℃，分离含有单组分的含H-硅氧烷的可加成交联的有机硅树脂的水相，并洗涤包含一个 - 组分，含H-硅氧烷的可加成交联的有机硅树脂，至少两个洗涤步骤，以减少残留的HCl含量，最后的洗涤使用0.01％-1.0％强度的碱的水溶液进行，pH为7.00-8.50 ，温度为20-50℃
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公开(公告)号：US5302683A
公开(公告)日：1994-04-12
申请号：US51911
申请日：1993-04-26
IPC分类号： B05D7/24 , C08G77/08 , C09D4/00 , C09D183/04
CPC分类号： C09D183/04 , C08G77/08 , C09D4/00
摘要： The present invention relates to a process for preparing coating compositions which comprises condensing a mixture containing (A) at least one silicone resin containing Si-bonded alkoxy groups and, if desired, silanol groups and/or at least one silane and/or siloxane which contains Si-bonded alkoxy groups and, if desired, silanol groups to form a silicone resin, (B) a basic condensation catalyst in an amount sufficient to render this mixture basic, (C) optionally water and (D) optionally an organic solvent.The resultant coating compositions are preferably employed in the form of a solution, emulsion or dispersion.
摘要翻译： 本发明涉及一种制备涂料组合物的方法，其包括将含有（A）至少一种含Si键合的烷氧基的有机硅树脂和（如果需要的话）硅烷醇基团和/或至少一种硅烷和/或硅氧烷的混合物 含有Si键合的烷氧基，如果需要，硅烷醇基以形成有机硅树脂，（B）碱性缩合催化剂的量足以使该混合物碱性，（C）任选的水和（D）任选的有机溶剂。 所得涂料组合物优选以溶液，乳液或分散体的形式使用。
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公开(公告)号：US20120203019A1
公开(公告)日：2012-08-09
申请号：US13501962
申请日：2010-10-06
IPC分类号： C07F7/18
CPC分类号： C07F7/21 , C07F7/0874
摘要： Silsesquisiloxanes are produced in high yield and purity in a minimal number of process steps by reacting quaternary ammonium silicates with disiloxanes in a precipitant liquid which causes the silsesquisiloxane product to be precipitated in high purity.
摘要翻译： 在最少数量的工艺步骤中通过使硅酸季铵与二硅氧烷在沉淀剂液体中反应而使硅硅氧烷产物以高纯度沉淀出来，以高产率和纯度生产硅聚硅氧烷。
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公开(公告)号：US07026427B2
公开(公告)日：2006-04-11
申请号：US10655977
申请日：2003-09-05
IPC分类号： C08G77/08
CPC分类号： C08G77/06
摘要： A process for the preparation of organopolysiloxane resins, wherein a silane R3SiOR1 (I) or a hydrolyzate thereof, and a silane Si(OR2)4 (II) or a partial hydrolyzate thereof, are reacted with acidified water and a portion of alcohol distilled off; the mixture is then reacted in the presence of base and a water-insoluble organic solvent and water, alcohol and optionally a portion of water-insoluble organic solvent are removed; the mixture is then neutralized with acid, and any water, alcohol, and a portion of organic solvent are distilled off; the mixture obtained is then treated with organopolysiloxanes and precipitated salts formed are then removed, and optionally, the mixture is separated from water-insoluble organic solvent.
摘要翻译： 一种制备有机聚硅氧烷树脂的方法，其中硅烷<？在线配方描述=“在线配方”末端=“铅”→R 3 SiOR 1 SUP>（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>或其水解产物，硅烷<？in-line-formula description =“In-line Formulas” end =“lead”？Si（OR 2）4（II）<？in-line-formula description =“In-line Formulas”end =“tail” 或其部分水解产物与酸化水反应，并蒸馏除去部分醇; 然后将混合物在碱和水不溶性有机溶剂的存在下反应，除去水，醇和任选的一部分水不溶性有机溶剂; 然后用酸中和混合物，并蒸去任何水，醇和一部分有机溶剂; 然后将所得混合物用有机聚硅氧烷处理，然后除去所形成的沉淀的盐，任选地，将混合物与水不溶性有机溶剂分离。
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公开(公告)号：US06232423B1
公开(公告)日：2001-05-15
申请号：US09413123
申请日：1999-10-06
IPC分类号： C08G7708
CPC分类号： C07F7/0874 , C08G77/045 , C08G77/06
摘要： Mixtures of linear organopolysiloxanes of the general formula 1 for R3SiO—(SiR2O)n—SiR3 (1) are produced by a process in which organochlorosilanes of the general formula 2 R4−ySiCly (2) where R is identical or different and is a hydrogen atom or an unsubstituted or substituted hydrocarbon radical having from 1 to 18 carbon atoms, Y is 1 or 2, and n is 0 or an integer from 1 to 50, are reacted continuously in a closed circulation system with water which may, if desired, have been acidified with hydrochloric acid, where the HCl concentration in the hydrochloric acid discharged is less than 25% by weight. Low molecular weight oligomer mixtures substantially free of both cyclic organosiloxanes and organosilicon compounds containing Si—Cl are economically produced.
摘要翻译： 通式1的线性有机聚硅氧烷的混合物是通过通式2其中R的有机氯硅烷相同或不同并且是氢原子或具有1至18个碳原子的未取代或取代的烃基的方法制备的，Y为1或 2和n为0或1至50的整数，在封闭循环系统中连续反应，并且如果需要，可用盐酸酸化，其中排出的盐酸中的HCl浓度小于25％ 重量。 经济地制造了基本上不含环状有机硅氧烷和含有Si-Cl的有机硅化合物的低分子量低聚物混合物。
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