发明授权
- 专利标题: Method for preparation of polycarbonates
- 专利标题(中): 聚碳酸酯的制备方法
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申请号: US09567826申请日: 2000-05-09
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公开(公告)号: US06277946B1公开(公告)日: 2001-08-21
- 发明人: Johannes Jacobus van Heijkant , Christopher Poirier , Tomoaki Shimoda , Akio Kanezawa , Carlos Godinez Seoane
- 申请人: Johannes Jacobus van Heijkant , Christopher Poirier , Tomoaki Shimoda , Akio Kanezawa , Carlos Godinez Seoane
- 优先权: ES200000385 20000218
- 主分类号: C08G6400
- IPC分类号: C08G6400
摘要:
A method is provided for the preparation of polycarbonates by the reaction of a diaryl carbonate, such as DPC and a dihydric phenol, such as BPA. The method utilizes the steps of successively processing the diaryl carbonate and the dihydric phenol in a melt in a first reaction stage, a second reaction stage and at least a first polymerization stage, and shifts the processing conditions such that the desired low viscosity/high end-cap product is obtained. This is achieved by having the ratio of diaryl carbonate to dihydric phenol in the melt prior to the first reaction stage greater than 1.08; and by controlling the temperature and residence time in the first polymerization stage to provide a polycarbonate product having a melt flow rate at 250° C. of greater than 10 g/min and an end-cap level of at least 90%. The method of the invention can be used in a linear manufacturing process, in which there is one product produced. The method of the invention can also be incorporated into a multi-line manufacturing process for the simultaneous production of more than one product. Thus, a stream of product produced from the first polymerization stage may be split into two or more lines which are further processed to produce, for example, a low viscosity, high end-cap product and a medium viscosity, moderate end-cap product.
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