发明授权
US06284931B1 Process for producing 3, 3, 5-trimethylcyclohexylidenebisphenol
有权
制备3,3,5-三甲基亚环己基双酚的方法
- 专利标题: Process for producing 3, 3, 5-trimethylcyclohexylidenebisphenol
- 专利标题(中): 制备3,3,5-三甲基亚环己基双酚的方法
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申请号: US09421372申请日: 1999-10-20
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公开(公告)号: US06284931B1公开(公告)日: 2001-09-04
- 发明人: Yoichiro Isota , Toru Nakaguchi , Hiroshi Takenaka , Kazuhiko Yao
- 申请人: Yoichiro Isota , Toru Nakaguchi , Hiroshi Takenaka , Kazuhiko Yao
- 优先权: JP10-298204 19981020
- 主分类号: C07L3917
- IPC分类号: C07L3917
摘要:
A process for producing a 3,3,5-trimethylcyclohexylidenebisphenol, comprising pre-reacting a phenol (A), i.e., phenol whose 2- and 6-positions may be monosubstituted or disubstituted with an alkyl group having 1 to 4 carbon atoms, with 3,3,5-trimethylcyclohexanone (B) at a molar ratio ((A)/(B)) of 3 to 7 in the presence of an acid catalyst until 3,3,5-trimethylcyclohexanone (B) exhibits a degree of conversion of at least 90 mol %; adding the phenol (A) and/or an aromatic hydrocarbon (C) to the thus obtained reaction mixture; and post-reacting the resultant mixture. This process enables not only suppressing a rise of the viscosity of the reaction mixture but also obtaining the desired product at high yield. Therefore, this process is applicable to not only the productivity enhancement in batch processing but also a continuous reaction processing which has been regarded as being difficult.
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