A multiple step chemical vapor deposition process for depositing a tungsten silicide layer on a substrate. A first step of the deposition process includes a pretreatment step in which WF6 is introduced into a deposition chamber. Next, the introduction of WF6 is stopped and a silicon-containing gas, e.g., SiH4, is introduced into the chamber. Finally, during a third step, the SiH4 flow is stopped and DCS and WF6 are introduced into the chamber to deposit a tungsten silicide layer on the substrate.