Invention Grant
US06365537B1 Two-component supported catalysts and their use for gas-phase polymerization 失效
双组分负载催化剂及其在气相聚合中的应用

  • Patent Title: Two-component supported catalysts and their use for gas-phase polymerization
  • Patent Title (中): 双组分负载催化剂及其在气相聚合中的应用
  • Application No.: US09151828
    Application Date: 1998-09-11
  • Publication No.: US06365537B1
    Publication Date: 2002-04-02
  • Inventor: Heike WindischNorbert Steinhauser
  • Applicant: Heike WindischNorbert Steinhauser
  • Priority: DE19741402 19970919
  • Main IPC: B01J3100
  • IPC: B01J3100
Two-component supported catalysts and their use for gas-phase polymerization
Abstract:
The present invention relates to a two-component supported catalyst, consisting of a) at least one transition metal compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the d and f elements of the periodic table according to Mendeleev, b) at least one organometallic compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the IIa, IIb and IIIb elements of the periodic table (F. A. Cotton, G. Wilkinson, Anorganische Chemie, 4th edition, VCH Verlagsgesellschaft mbH, Weinheim, 1985) and c) optionally at least one modifier which is supported on a) and/or on b), the transition metal compound in component a) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and the organometallic compound in component b) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and component c) being used in quantities of 0.01 to 500 mmol, based on 100 g of the supporting material, and the supporting materials of components a) to b) being used in quantitative ratios by weight (g/g) of 1.10−3 to 1000, and at least one of components a) or b) having a supporting material with an average particle size before or during polymerisation of
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