发明授权
- 专利标题: Nitration or carboxylation catalysts
- 专利标题(中): 硝化或羧化催化剂
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申请号: US09142089申请日: 1999-02-19
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公开(公告)号: US06468487B1公开(公告)日: 2002-10-22
- 发明人: Yasutaka Ishii , Tatsuya Nakano , Satoshi Sakaguchi
- 申请人: Yasutaka Ishii , Tatsuya Nakano , Satoshi Sakaguchi
- 优先权: JP9/4439 19970114; JP9/32440 19970217; JP9/209430 19970804
- 主分类号: B01J800
- IPC分类号: B01J800
摘要:
In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1): wherein R1 and R2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group and a cycloalkyl group, and R1 and R2 may bond together to form a double bond, or an aromatic or non-aromatic ring, and Y is an O or OH, and n denotes 1 to 3; a substrate is allowed to contact with at least one reactant selected from (i) a nitrogen oxide and (ii) a mixture of carbon monoxide and oxygen to be introduced with at least one functional group selected from a nitro group and a carboxyl group. The nitrogen oxide includes, for example, a compound represented by the formula NxOy (e.g., N2O3, NO2). The substrate includes, for example, a compound having a methine carbon atom (e.g., adamantane), a compound having a methyl group or a methylene group at an adjacent moiety of an aromatic ring. According to such reaction, the substrate can be efficiently nitrated or carboxylated even in a mild or moderate condition.