发明授权
- 专利标题: Process for manufacture of bisphenols
- 专利标题(中): 双酚制造工艺
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申请号: US10248155申请日: 2002-12-20
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公开(公告)号: US06635788B1公开(公告)日: 2003-10-21
- 发明人: Martin Herke Oyevaar , Rudy Francois Alain Jos Peemans , Eduard Hendricus Schlarmann
- 申请人: Martin Herke Oyevaar , Rudy Francois Alain Jos Peemans , Eduard Hendricus Schlarmann
- 主分类号: C07C3916
- IPC分类号: C07C3916
摘要:
A method for the manufacture of bisphenols comprises introducing a combined feed stream comprising a feed stream and a recycle stream into a reactor system comprising at least one reactor containing a catalytic proportion of an acid catalyst and wherein the combined feed stream comprises a carbonyl compound and a stoichiometric excess of phenol; removing from the reactor system a reactor effluent; splitting the reactor effluent into a crystallization feed stream and an effluent recycle stream; extracting from said crystallization feed stream a bisphenol adduct, remainder comprising a mother liquor stream; dehydrating said mother liquor stream and said effluent recycle stream in a dehydrator wherein excess water and carbonyl compound are removed; and recycling the dehydrated mother liquor and the dehydrated effluent recycle stream back to the combined feed stream to effect improved production of p,p-bisphenol, along with increased reactor selectivity and reduced promoter quantities.
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