发明授权
- 专利标题： Ether and ester derivatives of the perborate icosahedron
- 专利标题（中）： 过硼酸二十面体的醚和酯衍生物
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申请号： US09592214申请日： 2000-06-12
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公开(公告)号： US06664426B1公开(公告)日： 2003-12-16
- 发明人: M. Frederick Hawthorne , Toralf Peymann , Andreas Maderna
- 申请人： M. Frederick Hawthorne , Toralf Peymann , Andreas Maderna
- 主分类号： C07F502
- IPC分类号： C07F502
摘要：
New boron icosahedral ethers and esters formed from Cs2[closo-B12(OH)12],; Cs[closo-1-H-1-CB11(OH)11]; and closo-1,12-H2-1,12-C2B10(OH)10 are disclosed. Also set forth are their preparation by reacting the icosahedral boranes [closo-B12H12]2−, [closo-1-CB11H12]− and closo-1,12-(CH2OH)2-1,12-C2B10H10 with an acid anhdride or acid chloride to form the ester or an alkylating agent to form the ether.
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