In a toner production process having at least a kneading step, a pulverization step using a mechanical grinding machine, and a classification step, the grinding means comprises a mechanical grinding machine having at least a rotor which is a rotator attached to the center rotating shaft and a stator which is provided around the rotor, keeping a constant gap between the stator and the rotor surface, the grinding machine being so constructed that a circular space formed by keeping the gap stands airtight, and the surface of at least one of the rotor and the stator is coated by the plating of a chromium alloy containing at least chromium carbide.