Invention Grant
- Patent Title: Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
- Patent Title (中): 在烯烃聚合中的茂金属催化剂的活化剂固体载体,制备这种载体的方法以及相应的催化体系和聚合方法
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Application No.: US10402939Application Date: 2003-04-01
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Publication No.: US06780946B2Publication Date: 2004-08-24
- Inventor: Thierry Saudemont , Roger Spitz , Jean-Pierre Broyer , Jean Malinge , Nathalie Verdel
- Applicant: Thierry Saudemont , Roger Spitz , Jean-Pierre Broyer , Jean Malinge , Nathalie Verdel
- Priority: FR9712270 19971002
- Main IPC: C08F464
- IPC: C08F464

Abstract:
Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminum and/or magnesium Lewis-acid sites of formula: groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.
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