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    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    4.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 失效
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06780946B2

    公开(公告)日：2004-08-24

    申请号：US10402939

    申请日：2003-04-01

    申请人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    发明人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC分类号： C08F464

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    摘要： Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminum and/or magnesium Lewis-acid sites of formula: groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    摘要翻译： 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带下式的铝和/或镁路易斯酸位点：来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。

    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    5.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 有权
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06605561B1

    公开(公告)日：2003-08-12

    申请号：US09822840

    申请日：2001-04-02

    申请人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    发明人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC分类号： B01J3116

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    摘要： Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: or —Mg—F, the groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    摘要翻译： 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带式：或-Mg-F的铝和/或镁路易斯酸位点，来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应已经 随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。