发明授权
- 专利标题: Supported metallocene catalysts
- 专利标题(中): 负载金属茂催化剂
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申请号: US10412372申请日: 2003-04-11
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公开(公告)号: US06855783B2公开(公告)日: 2005-02-15
- 发明人: William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
- 申请人: William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
- 申请人地址: US TX Houston
- 专利权人: Fina Technology, Inc.
- 当前专利权人: Fina Technology, Inc.
- 当前专利权人地址: US TX Houston
- 代理商 Tenley R. Krueger
- 主分类号: B01J31/00
- IPC分类号: B01J31/00 ; B01J37/00 ; C07F9/00 ; C07F11/00 ; C07F17/00 ; C08F4/02 ; C08F4/42 ; C08F4/44 ; C08F4/60 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F110/02 ; C08F110/06
摘要:
Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C3+ ethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m2/g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). Alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Fl′)MQ2 in which Fl′ is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Fl′, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a Cl-C4 alkyl group.
公开/授权文献
- US20040204310A1 Supported metallocene catalysts 公开/授权日:2004-10-14
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