发明授权
- 专利标题: Process for producing hydrogen-containing gas
- 专利标题(中): 含氢气体的制造方法
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申请号: US10291375申请日: 2002-11-12
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公开(公告)号: US06916458B2公开(公告)日: 2005-07-12
- 发明人: Yasuhiro Kushida , Masayuki Katagiri , Hutoshi Ikoma , Shigeyuki Hirose , Yasushi Hiramatsu , Mikio Yoneoka
- 申请人: Yasuhiro Kushida , Masayuki Katagiri , Hutoshi Ikoma , Shigeyuki Hirose , Yasushi Hiramatsu , Mikio Yoneoka
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JP Tokyo
- 代理机构: Antonelli, Terry, Stout & Kraus, LLP
- 优先权: JP2001-354728 20011120; JP2001-354730 20011120; JP2001-357303 20011122; JP2001-400195 20011228
- 主分类号: B01J23/56
- IPC分类号: B01J23/56 ; B01J23/60 ; B01J23/62 ; B01J23/644 ; B01J23/652 ; B01J23/89 ; B01J35/04 ; B01J37/02 ; B01J37/03 ; C01B3/32 ; C01B3/26
摘要:
There is disclosed a process for producing a hydrogen-containing gas, which comprises reacting methanol, steam and oxygen in the presence of a catalyst comprising palladium, zinc and at least one metal selected from the group consisting of chromium, gallium, copper, indium, bismuth and platinum. That is to say, the process include the following four aspects: (I) a process which comprises reacting methanol, steam and oxygen in the presence of a catalyst comprising palladium, zinc, and either or both of chromium and gallium; (II) a process which comprises reacting methanol, steam and oxygen in the presence of a catalyst comprising palladium, zinc, copper and chromium; (III) a process which comprises reacting methanol, steam and oxygen in the presence of a catalyst comprising palladium and zinc, or chromium added thereto optionally, and either or both of indium and bismuth; and (IV) a process which comprises reacting methanol, steam and oxygen in the presence of a catalyst comprising zinc oxide, palladium and platinum. The use of the above steam-reforming catalyst having a high activity, high selectivity and sufficient durability makes it possible to produce a hydrogen-containing gas which is composed principally of hydrogen and minimized in CO concentration in an industrially advantageous manner through an auto thermal reformer where methanol, steam and oxygen are reacted with one another.
公开/授权文献
- US20030157019A1 Process for producing hydrogen-containing gas 公开/授权日:2003-08-21
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