Invention Grant
- Patent Title: Process for preparing TCD-alcohol DM
- Patent Title (中): 制备TCD-醇DM的方法
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Application No.: US10967580Application Date: 2004-10-18
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Publication No.: US06939997B2Publication Date: 2005-09-06
- Inventor: Peter Lappe , Helmut Springer , Rainer Lukas
- Applicant: Peter Lappe , Helmut Springer , Rainer Lukas
- Applicant Address: DE
- Assignee: Celanese Chemicals Europe GmbH
- Current Assignee: Celanese Chemicals Europe GmbH
- Current Assignee Address: DE
- Agent Charles A. Muserlian
- Priority: DE10352260 20031108
- Main IPC: B01J31/24
- IPC: B01J31/24 ; C07B61/00 ; C07C29/141 ; C07C29/16 ; C07C31/27 ; C07C45/50 ; C07C47/347 ; C07C47/445 ; C07C35/22

Abstract:
A process for preparing 3(4),8(9)-dihydroxymethyltricyclo[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent distillation wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane.
Public/Granted literature
- US20050107644A1 Process for preparing TCD-alcohol DM Public/Granted day:2005-05-19
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