发明授权
US06964692B2 Carbon monoxide adsorption for carbon monoxide clean-up in a fuel cell system
有权
一氧化碳吸附一氧化碳在燃料电池系统中的清理
- 专利标题: Carbon monoxide adsorption for carbon monoxide clean-up in a fuel cell system
- 专利标题(中): 一氧化碳吸附一氧化碳在燃料电池系统中的清理
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申请号: US09780184申请日: 2001-02-09
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公开(公告)号: US06964692B2公开(公告)日: 2005-11-15
- 发明人: Craig S. Gittleman , William H. Pettit , Gerald E. Voecks
- 申请人: Craig S. Gittleman , William H. Pettit , Gerald E. Voecks
- 申请人地址: US MI Detroit
- 专利权人: General Motors Corporation
- 当前专利权人: General Motors Corporation
- 当前专利权人地址: US MI Detroit
- 代理机构: Harness, Dickey & Pierce, P.L.C.
- 主分类号: B01D53/04
- IPC分类号: B01D53/04 ; B01D53/047 ; B01D53/06 ; B01J20/18 ; B01J20/20 ; C01B3/38 ; C01B3/48 ; C01B3/56 ; H01M8/06 ; H01M8/10 ; C10K3/04
摘要:
An apparatus removes carbon monoxide (CO) from a hydrogen-rich gas stream in a hydrogen fuel cell system. CO fouls costly catalytic particles in the membrane electrode assemblies of proton exchange membrane (PEM) fuel cells. A vessel houses a carbon monoxide adsorbent. The vessel may be a rotating pressure swing adsorber. A water gas shift reactor is upstream of the rotating pressure swing adsorber. The water gas shift reactor may include a second adsorbent adapted to adsorb carbon monoxide at low temperatures and to desorb carbon monoxide at high temperatures. The apparatus advantageously eliminates the use of a preferential oxidation (PROX) reactor, by providing an apparatus which incorporates CO adsorption in the place of the PROX reactor. This cleans up carbon monoxide without hydrogen consumption and the concomitant, undesirable excess low grade heat generation. The present invention reduces start-up duration, and improves overall fuel processor efficiency during normal operation.
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