Invention Grant
US07115774B2 Process for carbonylating alcohols, employing a catalyst based on rhodium or iridium in a non-aqueous ionic liquid, with efficient catalyst recycling 有权
在非水离子液体中使用基于铑或铱的催化剂羰基化醇的方法,具有有效的催化剂再循环

Process for carbonylating alcohols, employing a catalyst based on rhodium or iridium in a non-aqueous ionic liquid, with efficient catalyst recycling
Abstract:
In a process for liquid phase carbonylation of alcohols by carbon monoxide, the carbonylation reaction is carried out in a reaction zone at a temperature of 50° C. to 150° C. at a pressure in the range 0.5 MPa to 20 MPa in the presence of at least one catalyst comprising at least one rhodium and/or iridium complex and a halogenated promoter in at least one non-aqueous ionic liquid comprising at least one salt with general formula Q+A−, in which Q+ represents a quaternary ammonium and/or a quaternary phosphonium cation, said salt having a melting point of less than 90° C.; the non-aqueous ionic liquid containing at least the major portion of the catalyst is separated; and the separated non-aqueous ionic liquid containing at least the major portion of the catalyst is returned to the reaction zone.
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