发明授权
- 专利标题: Polymerization regulators and compositions for resin
- 专利标题(中): 聚合调节剂和树脂组合物
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申请号: US10297383申请日: 2002-04-04
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公开(公告)号: US07169845B2公开(公告)日: 2007-01-30
- 发明人: Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
- 申请人: Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JP Tokyo
- 代理机构: Antonelli, Terry, Stout and Kraus, LLP.
- 优先权: JP2001-109154 20010406; JP2001-139614 20010510
- 国际申请: PCT/JP02/03388 WO 20020404
- 国际公布: WO02/083763 WO 20021024
- 主分类号: C08L81/00
- IPC分类号: C08L81/00 ; C08K3/16
摘要:
In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1–C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1–C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13–16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1–C10 hydocarbyl or hydrogen, R4 is C1–C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1–C10 alkoxyl, C1–C10 alkylthio, or C1–C10 mercaptoalkythio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
公开/授权文献
- US20030171533A1 Polymerization regulators and compositions for resin 公开/授权日:2003-09-11
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