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公开(公告)号：US07169845B2
公开(公告)日：2007-01-30
申请号：US10297383
申请日：2002-04-04
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1–C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1–C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13–16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1–C10 hydocarbyl or hydrogen, R4 is C1–C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1–C10 alkoxyl, C1–C10 alkylthio, or C1–C10 mercaptoalkythio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ 1，R 2和R 3各自为C 1 -C 10氢碳基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C 1 -C 10烷氧基，C 1 -C 10烷硫基或C 1 -C 10巯基偶氮，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
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公开(公告)号：US07446163B2
公开(公告)日：2008-11-04
申请号：US11189859
申请日：2005-07-27
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
IPC分类号： C08G75/08
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ R 1，R 2和R 3各自为C 1 -C 10烃基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C1-C10烷氧基，C1-C10烷硫基或C1-C10巯基烷硫基，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
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公开(公告)号：US20050261467A1
公开(公告)日：2005-11-24
申请号：US11189859
申请日：2005-07-27
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
IPC分类号： C07D331/02 , C08G75/08 , C08G75/00
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ R 1，R 2和R 3各自为C 1 -C 10烃基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C1-C10烷氧基，C1-C10烷硫基或C1-C10巯基烷硫基，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
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公开(公告)号：US20060167217A1
公开(公告)日：2006-07-27
申请号：US10564056
申请日：2004-07-21
IPC分类号： C08K5/00 , C09D189/00 , C07D409/02
CPC分类号： G02B1/10 , B05D3/0272 , C08G75/08 , C09D181/02 , Y10T428/31533 , Y10T428/31663
摘要： There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.
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公开(公告)号：US08512813B2
公开(公告)日：2013-08-20
申请号：US13466964
申请日：2012-05-08
IPC分类号： B32B9/04
CPC分类号： G02B1/10 , B05D3/0272 , C08G75/08 , C09D181/02 , Y10T428/31533 , Y10T428/31663
摘要： There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.
摘要翻译： 提供具有良好润湿性的涂料组合物，其能够形成当聚合和固化时具有高折射率，较少变色和优异的透明度和均匀性的涂膜。 本发明涉及一种涂料组合物，其包含（A）100重量份的含有硫联环的化合物，（B）0.0001〜10重量份的用于促进含有含硫环环系化合物的聚合的催化剂和（C ）0.005〜4重量份改性硅油; 由该组合物制成的涂膜; 以及设有涂膜的光学产品。
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公开(公告)号：US20120219807A1
公开(公告)日：2012-08-30
申请号：US13466964
申请日：2012-05-08
CPC分类号： G02B1/10 , B05D3/0272 , C08G75/08 , C09D181/02 , Y10T428/31533 , Y10T428/31663
摘要： There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.
摘要翻译： 提供具有良好润湿性的涂料组合物，其能够形成当聚合和固化时具有高折射率，较少变色和优异的透明度和均匀性的涂膜。 本发明涉及一种涂料组合物，其包含（A）100重量份的含有硫联环的化合物，（B）0.0001〜10重量份的用于促进含有含硫环环系化合物的聚合的催化剂和（C ）0.005〜4重量份改性硅油; 由该组合物制成的涂膜; 以及设置有涂膜的光学产品。
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公开(公告)号：US20050227085A1
公开(公告)日：2005-10-13
申请号：US11101573
申请日：2005-04-08
CPC分类号： G02B1/04 , G02B1/041 , Y10T428/31533 , C08L81/02
摘要： A process for producing a hard-coated optical material. In the process, the hard coat is formed on the surface of plastic substrate after dipping the plastic substrate in an acidic substance without forming an intermediate layer such as a primer layer.
摘要翻译： 一种硬涂层光学材料的制造方法。 在此过程中，在将塑料基板浸渍在酸性物质中之后，在形成底漆层等中间层的状态下，在塑料基板表面上形成硬涂层。
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8.发明申请公开(公告)号：US20120123081A1
公开(公告)日：2012-05-17
申请号：US13383631
申请日：2010-07-12
申请人： Hiroyuki Okada , Hiroshi Horikoshi , Kenichi Toi
发明人： Hiroyuki Okada , Hiroshi Horikoshi , Kenichi Toi
CPC分类号： G02B1/04 , C08G18/3868 , C08G18/3874 , C08G18/3876 , C08G18/7642 , G02B1/041 , C08L81/00
摘要： The present invention is a production process for an optical material using, as raw materials thereof, a compound (a), a compound (b), a compound (c), a compound (d) and a compound (e) as shown below, the process comprising the following steps 1 to 5: Step 1: a step of obtaining a first liquid by dissolving the compound (b) in the compound (a); Step 2: a step of obtaining a second liquid by adding the compound (e) mixed with a portion of the compound (d) to the first liquid obtained in Step 1 and mixing the compound (e) mixed with a portion of the compound (d) with the first liquid uniformly; Step 3: a step of obtaining a reaction mixture by adding the compound (c) to the second liquid obtained in Step 2 and reacting the resulting mixture under reduced pressure; Step 4: a step of obtaining a resin composition for an optical material by adding the remainder of the compound (d) to the reaction mixture obtained in Step 3 and mixing the remainder of the compound (d) to the reaction mixture uniformly; and Step 5: a step of obtaining an optical material by casting and polymerizing the resin composition for an optical material obtained in Step 4.
摘要翻译： 本发明是使用如下所示的化合物（a），化合物（b），化合物（c），化合物（d）和化合物（e））作为原料的光学材料的制造方法。 该方法包括以下步骤1至5：步骤1：通过将化合物（b）溶解在化合物（a）中获得第一液体的步骤; 步骤2：通过将与化合物（d）的一部分混合的化合物（e）加入到步骤1中获得的第一液体中并混合化合物（e）与化合物的一部分（ d）与第一液体均匀; 步骤3：通过向步骤2中获得的第二液体中加入化合物（c）并在减压下使所得混合物反应获得反应混合物的步骤; 步骤4：通过向步骤3中获得的反应混合物中加入剩余的化合物（d）并将剩余的化合物（d）均匀混合到反应混合物中，获得光学材料用树脂组合物的步骤; 步骤5：通过浇铸和聚合步骤4中获得的光学材料用树脂组合物获得光学材料的步骤。
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9.发明授权公开(公告)号：US09182520B2
公开(公告)日：2015-11-10
申请号：US13383631
申请日：2010-07-12
申请人： Hiroyuki Okada , Hiroshi Horikoshi , Kenichi Toi
发明人： Hiroyuki Okada , Hiroshi Horikoshi , Kenichi Toi
CPC分类号： G02B1/04 , C08G18/3868 , C08G18/3874 , C08G18/3876 , C08G18/7642 , G02B1/041 , C08L81/00
摘要： The present invention provides an optical material, an optical lens, and a production process for making the same. The production process includes a step of obtaining a first liquid by dissolving a compound (b) in compound (a); a step of obtaining a second liquid by adding a compound (e) mixed with a portion of a compound (d) to the first liquid and mixing; a step of obtaining a reaction mixture by adding a compound (c) to the second liquid and reacting the resulting mixture under reduced pressure; a step of obtaining a resin composition for an optical material by adding the remainder of the compound (d) to the reaction mixture and mixing; and a step of obtaining an optical material by casting and polymerizing the resin composition.
摘要翻译： 本发明提供一种光学材料，光学透镜及其制造方法。 制备方法包括通过将化合物（b）溶解在化合物（a）中获得第一液体的步骤; 通过将与化合物（d）的一部分混合的化合物（e）加入到第一液体中并混合而获得第二液体的步骤; 通过向第二液体中加入化合物（c）并在减压下使所得混合物反应获得反应混合物的步骤; 通过将剩余的化合物（d）加入到反应混合物中并混合获得用于光学材料的树脂组合物的步骤; 以及通过浇铸和聚合树脂组合物获得光学材料的步骤。
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公开(公告)号：US09186803B2
公开(公告)日：2015-11-17
申请号：US13581425
申请日：2011-03-24
CPC分类号： B26B19/384 , B26B19/143 , B26B19/38 , B26B19/3893
摘要： An electric shaver includes an outer blade having blade holes defined by a frame, and an inner blade provided inside the outer blade to move relative to the outer blade and cut body hair inserted into the blade holes. Circumferences of the blade holes of the frame are bent toward the inner blade so as to provide hair lifting portions having rounded portions in the frame, and the frame provided with the hair lifting portions is located closer to a skin than to a surface of the inner blade on a skin side.
摘要翻译： 电动剃须刀包括具有由框架限定的刀片孔的外刀片和设置在外刀片内部的内刀片，以相对于外刀片移动并插入刀片孔中的切割体毛发。 框架的叶片孔的周缘向内侧刀片弯曲，以便在框架中提供具有圆形部分的头发提升部分，并且设置有毛发提升部分的框架位于比内部的表面更靠近皮肤的位置 刀片在皮肤一侧。
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