发明授权
US07196146B2 Method for producing aqueous styrene-butadiene polymer dispersions II
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制备苯乙烯 - 丁二烯聚合物水分散体的方法II
- 专利标题: Method for producing aqueous styrene-butadiene polymer dispersions II
- 专利标题(中): 制备苯乙烯 - 丁二烯聚合物水分散体的方法II
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申请号: US10491336申请日: 2002-09-30
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公开(公告)号: US07196146B2公开(公告)日: 2007-03-27
- 发明人: Lambertus Manders , Thomas Wirth , Wolfgang Gaschler , Hubertus Kroener
- 申请人: Lambertus Manders , Thomas Wirth , Wolfgang Gaschler , Hubertus Kroener
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, P.C.
- 优先权: DE10148496.8 20011001
- 国际申请: PCT/EP02/10967 WO 20020930
- 国际公布: WO03/029314 WO 20030410
- 主分类号: C08F2/22
- IPC分类号: C08F2/22 ; C08F236/10
摘要:
A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and α-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.
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