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1.发明授权公开(公告)号：US07375148B2
公开(公告)日：2008-05-20
申请号：US10491279
申请日：2002-09-30
CPC分类号： C08F212/08 , C08F236/10 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising styrene, butadiene, and if desired up to 30% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; in a polymerization vessel by a monomer feed technique in the presence of a regulator system containing, based on 100% by weight of monomers, from 0.02 to 0.5% by weight of at least one hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or 1-phenylallyl radical, and α-methylstyrene dimer, and from 0.3 to 2% by weight of an organic compound S containing at least one SH group wherein at least 30%, preferably at least 50%, in particular at least 80%, and with particular preference the entirety (or >95%) of hydrocarbon HC is included in the initial charge to the polymerization vessel.
摘要翻译： 一种通过自由基水性乳液聚合制备含苯乙烯，丁二烯的单体混合物M，如果需要，基于100重量％的单体为30重量％的烯属不饱和单体 苯乙烯和丁二烯以外的共聚单体; 在聚合容器中通过单体进料技术在含有基于100重量％单体的0.02至0.5重量％的至少一种具有6至20个碳原子的烃HC的调节剂体系的存在下，选自 取代氢原子形成戊二烯基或1-苯基烯丙基的化合物和α-甲基苯乙烯二聚体，以及0.3至2重量％的含有至少一个SH基团的有机化合物S，其中至少30％，优选 至少50％，特别是至少80％，特别优选的是，在聚合容器的初始装料中包括烃HC的全部（或> 95％）。
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公开(公告)号：US07858154B2
公开(公告)日：2010-12-28
申请号：US11719219
申请日：2005-11-05
CPC分类号： D21H19/58 , D21H19/42 , Y10T428/31895
摘要： A paper coating slip comprising at least one inorganic pigment and, based on 100 parts by weight of the inorganic pigments, less than 40 parts by weight of organic polymers, and less than 25 parts by weight of water or other solvents having a boiling point below 150° C. at 1 bar.
摘要翻译： 包含至少一种无机颜料的纸涂层滑爽剂，基于100重量份的无机颜料，少于40重量份的有机聚合物和小于25重量份的沸点低于25重量份的水或其它溶剂 150℃，1巴。
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3.发明授权公开(公告)号：US07282545B2
公开(公告)日：2007-10-16
申请号：US10491283
申请日：2002-09-30
CPC分类号： C08F212/08 , C08F236/10 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from α-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.
摘要翻译： 一种通过自由基水性乳液聚合制备含40至80重量％苯乙烯作为单体M1的单体混合物M，20至60重量％的作为单体M2的丁二烯的丁二烯聚合物水分散体的方法， 和0至40重量％，基于100重量％的单体，除了苯乙烯和丁二烯之外的烯键式不饱和共聚单体M3，通过单体进料技术，在0.05至0.5重量％的存在下，基于100重量％ 至少一种具有6至20个碳原子的烃HC的重量，其选自从氢原子形成戊二烯基或1-苯基烯丙基和由α-甲基苯乙烯二聚体构成的化合物包括至少30 在初始加入到聚合容器中的烃HC的％，并且在该反应过程中将剩余的烃HC供应到聚合反应中。
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4.发明授权公开(公告)号：US07196146B2
公开(公告)日：2007-03-27
申请号：US10491336
申请日：2002-09-30
IPC分类号： C08F2/22 , C08F236/10
CPC分类号： C08F236/10 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and α-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.
摘要翻译： 一种通过自由基水性乳液聚合制备含40至80重量％苯乙烯作为单体M1的单体混合物M，20至60重量％的作为单体M2的丁二烯的丁二烯聚合物水分散体的方法， 和0至40重量％，基于100重量％的单体，除了苯乙烯和丁二烯之外的烯键式不饱和共聚单体M3，通过单体进料技术，在0.05至0.5重量％的存在下，基于100重量％ 至少一种选自氢原子取代氢原子形成戊二烯基或1-苯基烯丙基和α-甲基苯乙烯二聚体的化合物的至少一种具有6至20个碳原子的烃HC的单体重量包括在 至少70％的待聚合的单体已经被供应到聚合反应中，单体进料中丁二烯的浓度至少为总进料时间的1％，至少为10重量％，基于m 饲料中的异构体。
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公开(公告)号：US5369164A
公开(公告)日：1994-11-29
申请号：US135977
申请日：1993-10-14
申请人： Hubertus Kroener , Uwe Dittrich , Alexander Zettl
发明人： Hubertus Kroener , Uwe Dittrich , Alexander Zettl
IPC分类号： C08K5/06 , C09J4/02 , C09J133/06 , C14C11/00 , C08L51/06 , C09J133/08 , C09J133/10 , B32B7/12
CPC分类号： C14C11/003 , C08K5/06 , C09J133/06 , Y10T428/31855
摘要： An aqueous dispersion or solution of a polymer obtained by free radical polymerization and comprising from 0.01 to 10% by weight of carboxyl groups --CO.sub.2 H or sulfo groups --SO.sub.3 H contains, as a crosslinking agent, a compound having at least two vinyl ether groups.
摘要翻译： 通过自由基聚合获得的包含0.01至10重量％羧基-CO 2 H或磺基-SO 3 H的聚合物的水性分散体或溶液含有具有至少两个乙烯基醚基团的化合物作为交联剂。
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公开(公告)号：US07282547B2
公开(公告)日：2007-10-16
申请号：US10491271
申请日：2002-09-30
IPC分类号： C08F212/08 , C08F236/06
CPC分类号： C08F212/08 , C08F236/06 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from α-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.
摘要翻译： 一种通过自由基水性乳液聚合制备含40至80重量％苯乙烯作为单体M1的单体混合物M，20至60重量％的作为单体M2的丁二烯的丁二烯聚合物水分散体的方法， 和0至40重量％，基于100重量％的单体，除了苯乙烯和丁二烯之外的烯键式不饱和共聚单体M3，通过单体进料技术，在0.05至0.5重量％的存在下，基于100重量％ 单体的重量，至少一种选自具有6至20个碳原子的化合物的烃HC，其中取代氢原子形成戊二烯基或1-苯基烯丙基并且由α-甲基苯乙烯二聚体包括将待聚合的单体供应至 聚合反应在3小时的过程中。
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公开(公告)号：US5486586A
公开(公告)日：1996-01-23
申请号：US440119
申请日：1995-05-12
申请人： Hubertus Kroener , Eberhard Schupp , Eckehardt Wistuba , Oral Aydin , Elmar Schwarzenbach , Klaus Schnell
发明人： Hubertus Kroener , Eberhard Schupp , Eckehardt Wistuba , Oral Aydin , Elmar Schwarzenbach , Klaus Schnell
IPC分类号： C08F16/26 , C08F16/14 , C08F16/16 , C08F16/28 , C08F16/30 , C08F216/18 , C09J129/00 , C09J129/10 , C08F16/12
CPC分类号： C09J129/10
摘要： Adhesives containing polyvinyl ether copolymers having a weight average molecular weight of >10,000, comprisea) from 0 to 95% by weight of vinyl ethers of the formula IH.sub.2 C.dbd.CH--O--Rb) from 5 to 100% by weight of hydrophilic vinyl ethers of the formula IIH.sub.2 C.dbd.CH--O--R.sup.1andc) from 0 to 30% by weight of further monomers,where R is C.sub.1 -C.sub.20 -alkyl and R.sup.1 is an aliphatic or cycloaliphatic radical which may be substituted by hydroxyl groups or interrupted by nonadjacent groups --Y--, Y is oxygen, sulfur or a group NR.sup.2 or N.sup.+ R.sup.2 R.sup.3 X.sup.-, R.sup.2 and R.sup.3 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl and X.sup.- is a counter-anion, and the molar ratio of carbon atoms to the sum of groups Y and hydroxyl groups in the aliphatic or cycloaliphatic radical is from 1.01:1 to 6.5:1.
摘要翻译： 包含重均分子量> 10,000的聚乙烯醚共聚物的粘合剂包含a）0至95重量％的式I的乙烯基醚H 2 C = CH-OR b）5至100重量％的亲水乙烯基醚 的式IIH 2 C = CH-O-R 1和c）0至30重量％的另外的单体，其中R是C 1 -C 20 - 烷基，R 1是可以被羟基取代或被中断的脂族或脂环族基团 通过不相邻的基团-Y-，Y是氧，硫或基团NR2或N + R2R3X-，R2和R3彼此独立地各自是氢或C1-C4-烷基，X是抗衡阴离子， 脂肪族或脂环族基团中碳原子与基团Y和羟基之和的比例为1.01:1至6.5:1。
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