发明授权
- 专利标题: Uv-curable coating composition and coated articles
- 专利标题(中): 可紫外固化涂料组合物和涂层制品
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申请号: US10508326申请日: 2003-03-20
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公开(公告)号: US07235591B2公开(公告)日: 2007-06-26
- 发明人: Takeshi Tsunoda , Shinji Mitsumune
- 申请人: Takeshi Tsunoda , Shinji Mitsumune
- 申请人地址: JP Kanagawa
- 专利权人: BASF Coatings Japan Ltd.
- 当前专利权人: BASF Coatings Japan Ltd.
- 当前专利权人地址: JP Kanagawa
- 代理机构: Levy & Grandinetti
- 优先权: JP2002-080289 20020322; JP2002-155717 20020529; JP2002-318723 20021031
- 国际申请: PCT/JP03/03438 WO 20030320
- 国际公布: WO03/080745 WO 20031002
- 主分类号: C08F2/46
- IPC分类号: C08F2/46 ; C08F2/50
摘要:
The present invention relates to an ultraviolet-curable coating composition comprising: (A) an ultraviolet curable four or more functional groups-containing polyfunctional (meth)acrylate having four or more (meth)acryloyl groups in the molecule and a number average molecular weight of 300 to 2,000, (B) a lactone-modified polymer of polyhydric alcohol mono(meth)acrylate containing 20 to 60 percents by weight of ε-caprolactone ring-opening addition product and having a hydroxyl value derived from the lactone modification of 100 to 180 mgKOH/g, and/or a lactone-modified polyester resin containing 10 to 50 percents by weight of lactone ring-opening addition product and having a hydroxyl value of 50 to 180 mgKOH/g, (C) a non-yellow polyisocyanate compound and/or an amino resin, (D) a light stabilizer and, (E) a photopolymerization initiator, wherein a weight ratio of component (A) against to a total weight of component Components (B) and (C) is 10:90 to 50:50, a weight ratio of component (B) against to component (C) is 90:10 to 20:80, and the components described above are formulated to obtain a cured paint film having a Knoop hardness of 10 to 18 and a molecular weight of intercrosslinking of crosslinked resin component in the cured paint film of 150 to 300. The ultraviolet-curable coating composition of the present invention can form the cured paint film having excellent scratch resistance, aesthetic decorative property, adhesion and gasoline resistance, and has high productivity of paint film.
公开/授权文献
- US20050165125A1 Uv-curable coating composition and coated articles 公开/授权日:2005-07-28
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