发明授权
US07273540B2 Tin-silver-copper plating solution, plating film containing the same, and method for forming the plating film 有权
锡 - 银 - 铜电镀溶液,含有它们的镀膜和形成电镀膜的方法

Tin-silver-copper plating solution, plating film containing the same, and method for forming the plating film
摘要:
An electrolytic plating method, including: preparing a plating solution including water which is a primary medium, a sulfonic acid, and tin, copper, and silver ions, and a complexing agent, concentrations of the sulfonic acid, and tin, copper, and silver ions being 0.5 to 5 mol/L, 0.21 to 2 mol/L, 0.002 to 0.02 mol/L, and 0.01 to 0.1 mol/L, respectively, a mole ratio of the silver-ion concentration to the copper-ion concentration being in a range of 4.5 to 5.58; and separating a solution around a soluble anode containing 90 percent or more of tin from the plating solution on a cathode side by a non-ionic micro-porous membrane having a pore diameter of 0.01 to 0.05 μm and a thickness of 5 to 100 μm.
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