发明授权
US07288613B2 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
失效
N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合
- 专利标题： N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
- 专利标题（中）： N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合
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申请号： US11364537申请日： 2006-02-28
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公开(公告)号： US07288613B2公开(公告)日： 2007-10-30
- 发明人: Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
- 申请人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
- 申请人地址： US NY Tarrytown
- 专利权人： Ciba Specialty Chemicals Corp.
- 当前专利权人： Ciba Specialty Chemicals Corp.
- 当前专利权人地址： US NY Tarrytown
- 代理商 Tyler A. Stevenson
- 优先权： EP00811190 20001214
- 主分类号： C08F2/38
- IPC分类号： C08F2/38 ; C08F4/00
摘要：
The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
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