发明授权
- 专利标题: Process for preparing vulcanizable fluorine-containing elastomer
- 专利标题(中): 制备可硫化含氟弹性体的方法
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申请号: US10542545申请日: 2004-01-22
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公开(公告)号: US07375171B2公开(公告)日: 2008-05-20
- 发明人: Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
- 申请人: Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
- 申请人地址: JP Osaka
- 专利权人: Daikin Industries, Ltd.
- 当前专利权人: Daikin Industries, Ltd.
- 当前专利权人地址: JP Osaka
- 代理机构: Sughrue Mion, PLLC
- 优先权: JP2003-016788 20030124; JP2003-278545 20030723
- 国际申请: PCT/JP2004/000519 WO 20040122
- 国际公布: WO2004/065436 WO 20040805
- 主分类号: C08F14/18
- IPC分类号: C08F14/18
摘要:
The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1.Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
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