Process for preparing vulcanizable fluorine-containing elastomer
    4.
    发明申请
    Process for preparing vulcanizable fluorine-containing elastomer 有权
    制备可硫化含氟弹性体的方法

    公开(公告)号:US20070299207A1

    公开(公告)日:2007-12-27

    申请号:US11892702

    申请日:2007-08-27

    IPC分类号: C08L27/14

    摘要: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.

    摘要翻译: 本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。 本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。 该方法是在临界常数降低至少为0.95,临界常数降低至少为0.80的条件下进行的间歇共聚方法,其中降低的温度和减压是使用Peng-Robinson公式 在临界温度下,在具有下式的化合物的存在下,在反应容器中的气相中的每种单体的临界压力和组成比共聚,其中含有至少一个氟烯烃的烯键式不饱和化合物在具有下式的化合物的存在下共聚: 其中R 1是饱和或不饱和的氟代烃或其中R 1,R 2,R 3,R 4, 具有1至16个碳原子的氯氟烃基,x是R 1和...的整数1至4的整数。

    Transparent rare-earth oxide sintered body and manufacturing method thereof
    5.
    发明授权
    Transparent rare-earth oxide sintered body and manufacturing method thereof 有权
    透明稀土氧化物烧结体及其制造方法

    公开(公告)号:US07608553B2

    公开(公告)日:2009-10-27

    申请号:US11589795

    申请日:2006-10-31

    IPC分类号: C04B35/505

    摘要: The invention intends to obtain a transparent yttrium oxide sintered body of which in-line transmittance in a visible wavelength region of 400 to 800 nm at a thickness of 1 mm is 60% or more, without using aluminum that readily segregates in grain boundaries of yttrium oxide, without using special raw materials in which a silicon content is particularly reduced and without finely pulverizing raw materials. A transparent yttrium oxide sintered body that contains, with yttrium oxide as a main component, at least either one of tantalum or niobium or both thereof and has the in-line transmittance of 60% or more at a thickness of 1 mm in a visible wavelength region in the range of 400 to 800 nm.

    摘要翻译: 本发明旨在获得一种透明的氧化钇烧结体,其中在1mm至5mm的可见光波长范围内的直线透射率为60%以上,而不使用易于在钇的晶界中分离的铝 氧化物,而不使用其中硅含量特别降低的特殊原料,而不需要细粉碎原料。 一种透明氧化钇烧结体,其以氧化钇为主要成分,含有钽或铌中的至少一种或二者,并且在可见波长为1mm的条件下具有60%以上的直线透射率 范围在400至800nm之间。

    Process for preparing fluorine-containing polymer
    6.
    发明授权
    Process for preparing fluorine-containing polymer 有权
    含氟聚合物的制备方法

    公开(公告)号:US07345124B2

    公开(公告)日:2008-03-18

    申请号:US10521807

    申请日:2003-07-23

    IPC分类号: C08F14/18

    摘要: The present invention provides a process for preparing a fluorine-containing polymer having few branched chains and little weight change in high temperatures, which is a new process wherein composition distribution substantially does not occur. The fluorine-containing polymer is prepared by a batch copolymerization process conducted under conditions of reduced temperature of at least 0.95 and reduced pressure of at least 0.80 of the critical constant calculated from critical temperature, critical pressure and composition ratio of each monomer in the gaseous phase of the reaction vessel using the Peng-Robinson formula.

    摘要翻译: 本发明提供一种制备具有很少支链和在高温下重量变化小的含氟聚合物的方法,这是其中组合物分布基本上不发生的新方法。 含氟聚合物是通过间歇共聚方法制备的,所述间歇共聚方法是在降低至少0.95的温度和至少0.80的关键常数的减压条件下进行的,该临界常数由气相中各单体的临界温度,临界压力和组成比计算 的反应容器使用Peng-Robinson公式。

    Nitrile group-containing fluoroelastomer and preparation process of same
    7.
    发明授权
    Nitrile group-containing fluoroelastomer and preparation process of same 有权
    含腈基的含氟弹性体及其制备方法

    公开(公告)号:US06841625B2

    公开(公告)日:2005-01-11

    申请号:US10301726

    申请日:2002-11-22

    IPC分类号: C08F8/00 C08F8/30 C08F8/18

    CPC分类号: C08F8/00 C08F8/30 C08F214/18

    摘要: To provide a solid fluoroelastomer having nitrile group at the, end which gives a crosslinked product being excellent in heat resistance, solvent resistance, chemical resistance, compression set and cleanliness, and an economical process for preparation thereof. The process for preparing a nitrile group-containing fluoroelastomer by converting amide group contained in a polymer molecular chain of a solid fluoroelastomer into nitrile group in the presence of a dehydrating agent.

    摘要翻译: 为了提供具有优异的耐热性,耐溶剂性,耐化学性,压缩永久变形和清洁性的交联产物,以及其制备的经济方法,提供了一种具有腈基的固体含氟弹性体。 通过在脱水剂的存在下将固体含氟弹性体的聚合物分子链中所含的酰胺基团转化成腈基来制备含腈基的含氟弹性体的方法。

    Process for preparing vulcanizable fluorine-containing elastomer
    9.
    发明授权
    Process for preparing vulcanizable fluorine-containing elastomer 有权
    制备可硫化含氟弹性体的方法

    公开(公告)号:US08247505B2

    公开(公告)日:2012-08-21

    申请号:US11892702

    申请日:2007-08-27

    IPC分类号: C08F14/18

    摘要: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.

    摘要翻译: 本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。 本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。 该方法是在临界常数降低至少为0.95,临界常数降低至少为0.80的条件下进行的间歇共聚方法,其中降低的温度和减压是使用Peng-Robinson公式 在临界温度下,在具有下式的化合物的存在下共聚反应容器中气相中各单体的临界压力和组成比:Rf1· 其中Rf1是具有1至16个碳原子的饱和或不饱和的氟代烃或氯氟烃基,x是Rf1的键数和1至4的整数。

    PROCESS FOR PREPARING FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING POLYMER PREPARED BY SAID PREPARATION PROCESS
    10.
    发明申请
    PROCESS FOR PREPARING FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING POLYMER PREPARED BY SAID PREPARATION PROCESS 有权
    制备含氟聚合物和含有准分子过程制备的含氟聚合物的方法

    公开(公告)号:US20090082519A1

    公开(公告)日:2009-03-26

    申请号:US11913287

    申请日:2006-04-28

    IPC分类号: C08K3/04 C08F214/18 C08L27/22

    摘要: The present invention provides the process for preparing a fluorine-containing polymer which can easily and efficiently separate a fluorine-containing polymer and water from an aqueous dispersion of a fluorine-containing polymer, and the fluorine-containing polymer obtained by the mentioned preparation process. Further the present invention provides the molded article obtained by crosslinking a curable composition comprising the above-mentioned fluorine-containing polymer and a crosslinking agent. The preparation process is a process for preparing a fluorine-containing polymer comprising a step for heat-treating an aqueous dispersion of a fluorine-containing polymer having a concentration of 3 to 70% by weight to obtain the fluorine-containing polymer having a water content of not more than 1% by weight.

    摘要翻译: 本发明提供一种制备含氟聚合物的方法,其可以容易且有效地从含氟聚合物的水性分散体中分离含氟聚合物和水,以及通过所述制备方法得到的含氟聚合物。 此外,本发明提供通过交联含有上述含氟聚合物的固化性组合物和交联剂而得到的成型体。 制备方法是一种制备含氟聚合物的方法,其包括用于热处理浓度为3-70重量%的含氟聚合物的水性分散体的步骤,以获得含水量的含氟聚合物 不超过1重量%。