发明授权
- 专利标题: Method for the continuous production of an amine
- 专利标题(中): 连续生产胺的方法
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申请号: US11596292申请日: 2005-05-04
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公开(公告)号: US07405327B2公开(公告)日: 2008-07-29
- 发明人: Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
- 申请人: Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Connolly Bove Lodge & Hutz LLP
- 优先权: DE102004023529 20040513
- 国际申请: PCT/EP2005/004817 WO 20050504
- 国际公布: WO2005/110969 WO 20051124
- 主分类号: C07C209/26
- IPC分类号: C07C209/26
摘要:
Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
公开/授权文献
- US20070232833A1 Method for the Continuous Production of an Amine 公开/授权日:2007-10-04
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