A non-aqueous electrolyte secondary battery in which a positive electrode formed of a graphite powder and an negative electrode formed of a material capable of absorption/desorption of a lithium metal or lithium are placed to face each other in an electrolyte containing lithium salt. The positive electrode of this battery where a Lc (112) which is the size of crystallite in a c axis direction which is calculated from a (112) diffraction line of a graphite crystal and determined by a powder X-ray diffraction method which is from 4 nm to 30 nm, and a charge capacity at the first cycle which is calculated on the basis of a total weight of the graphite material of the positive electrode filled in the battery is 20 to 50 (mAh/g). Preferably, the graphite powder of the positive electrode has an ratio (A/B) which is the ratio of a specific surface area A determined by a nitrogen absorption (BET) method to a surface area B determined on the basis of an area average diameter of 20 or less.