A semiconductor device includes a semiconductor substrate including silicon and an oxide layer on the substrate. The oxide layer includes silicon. An interfacial dielectric layer is disposed on the oxide layer opposite the substrate. The interfacial dielectric layer includes HfO2, ZrO2, a zirconium silicate alloy, and/or a hafnium silicate alloy having a thickness between about 0.5 nm and 1.0 nm. A primary dielectric layer is disposed on the interfacial dielectric layer opposite the substrate. The primary dielectric layer includes AlO3; TiO2; a group IIIB or VB transition metal oxide; a trivalent lanthanide series rare earth oxide; a silicate alloy; an aluminate alloy; a complex binary oxide having two transition metal oxides and/or a complex binary oxide having a transition metal oxide and a lanthanide rare earth oxide. A thickness of the primary dielectric layer is at least about five times greater than the thickness of the interfacial dielectric layer.