发明授权
- 专利标题: Integrate chemical processes for industrial utilization of seed oils
- 专利标题(中): 整合化学工业用于种子油的工业利用
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申请号: US10508805申请日: 2003-04-17
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公开(公告)号: US07576227B2公开(公告)日: 2009-08-18
- 发明人: Zenon Lysenko , Bob R. Maughon , Josef Bicerano , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettlof , Jerry E. White
- 申请人: Zenon Lysenko , Bob R. Maughon , Josef Bicerano , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettlof , Jerry E. White
- 申请人地址: US MI Midland
- 专利权人: Union Carbide Chemicals & Plastics Technology Corporation
- 当前专利权人: Union Carbide Chemicals & Plastics Technology Corporation
- 当前专利权人地址: US MI Midland
- 国际申请: PCT/US03/11852 WO 20030417
- 国际公布: WO03/093245 WO 20031113
- 主分类号: C07C57/00
- IPC分类号: C07C57/00 ; C07C53/00
摘要:
Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ωpolyester polyamine.
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