公开(公告)号：US07119216B2

公开(公告)日：2006-10-10

申请号：US10469321

申请日：2002-02-27

申请人： Thomas H. Newman ,  Cynthia L. Rand ,  Kenneth A. Burdett ,  Bob R. Maughon ,  Donald L. Morrison ,  Eric P. Wasserman

发明人： Thomas H. Newman ,  Cynthia L. Rand ,  Kenneth A. Burdett ,  Bob R. Maughon ,  Donald L. Morrison ,  Eric P. Wasserman

IPC分类号： C11C3/00

CPC分类号： C07C51/353 ,  B01J31/1658 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/28 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07C7/04 ,  C07C7/12 ,  C07C67/333 ,  Y02P20/127 ,  C07C11/02 ,  C07C57/03 ,  C07C69/533

摘要： An olefin metathesis process involving contacting an unsaturated fatty acid ester or unsaturated fatty acid, such as methyloleate or oleic acid, with a lower olefin, preferably ethylene, in the presence of a metathesis catalyst so as to prepare a first product olefin, preferably, a reduced chain α-olefin, such as methyl-9-decenoate or 9-decenoic acid, respectively. The metathesis catalyst contains ruthenium or osmium and a chelating ligand, preferably, a chelating ligand containing a carbene moiety and a second donor moiety of a Group 15 or 16 element Optionally, the catalyst can be supported on a catalyst support, such as, a cross-linked polymeric resin.

摘要翻译： 一种烯烃复分解方法，包括使不饱和脂肪酸酯或不饱和脂肪酸如羟甲基或油酸与复分解催化剂存在下使低级烯烃（优选乙烯）接触，以制备第一产物烯烃，优选为 还原链α-烯烃，如9-癸烯酸甲酯或9-癸烯酸。 复分解催化剂含有钌或锇和螯合配体，优选含有卡宾部分和第15或16族元素的第二供体部分的螯合配体任选地，催化剂可负载在催化剂载体上，例如十字 连接的聚合物树脂。

公开(公告)号：US06350922B1

公开(公告)日：2002-02-26

申请号：US09464682

申请日：1999-12-16

申请人： Paul C. Vosejpka ,  Dennis A. Hucul ,  Bob R. Maughon ,  Larry N. Ito ,  Robert M. Campbell

发明人： Paul C. Vosejpka ,  Dennis A. Hucul ,  Bob R. Maughon ,  Larry N. Ito ,  Robert M. Campbell

IPC分类号： C07C2938

CPC分类号： C07C29/141 ,  C07C31/36

摘要： A process for making 2,3-dihalopropanol including reacting 2,3-dihalopropanal with a hydrogenating agent in the presence of an iridium and a second transition metal mixed metal catalyst where the second transition metal is selected from the group comprising ruthenium, iron, molybdenum, tungsten, rhenium, osmium, manganese or vanadium, under conditions such that 2,3-dihalopropanol is formed. The 2,3-dihalopropanol is particularly useful in a process for making epihalohydrin.

摘要翻译： 一种制备2,3-二卤丙醇的方法，包括在铱和第二过渡金属混合金属催化剂存在下使2,3-二卤代丙醛与氢化剂反应，其中第二过渡金属选自钌，铁，钼 钨，铼，锇，锰或钒，形成2,3-二卤丙醇的条件下进行。 2,3-二卤丙醇在制备表卤代醇的方法中特别有用。

公开(公告)号：US07576227B2

公开(公告)日：2009-08-18

申请号：US10508805

申请日：2003-04-17

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Josef Bicerano ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettlof ,  Jerry E. White

IPC分类号： C07C57/00 ,  C07C53/00

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ωpolyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US07176336B2

公开(公告)日：2007-02-13

申请号：US10940403

申请日：2004-09-14

申请人： Bob R. Maughon ,  Kenneth A. Burdett ,  Zenon Lysenko

发明人： Bob R. Maughon ,  Kenneth A. Burdett ,  Zenon Lysenko

IPC分类号： C07C29/00 ,  C07C33/025 ,  C07C33/03

CPC分类号： C07C29/095 ,  C07C67/293 ,  C07C67/333 ,  C07C67/475 ,  C07C69/007 ,  C07C69/533 ,  C07C69/593 ,  C07C69/145 ,  C07C33/03 ,  C07C33/035

摘要： A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

摘要翻译： 一种制备不饱和醇（烯烃）的方法，例如均聚单醇或均烯基多元醇，包括保护羟基取代的不饱和脂肪酸或脂肪酸酯如蓖麻油酸甲酯，其衍生自 种子油，形成羟基保护的不饱和脂肪酸或脂肪酸酯; 羟基保护的不饱和脂肪酸或脂肪酸酯的均匀化或交叉变性以产生含有羟基保护的非饱和复分解产物的产物混合物; 并在足以制备不饱和醇的条件下脱保护羟基保护的不饱和复分解产物。 优选地，蓖麻油酸甲酯通过交叉复分解或均一复分解转化成均相烯醇1-癸烯-4-醇或均烯基多元醇9-十八碳烯-7,12-二醇。

公开(公告)号：US20090143544A1

公开(公告)日：2009-06-04

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C08L63/08 ,  C07C51/43 ,  C07C59/42 ,  C07C31/18 ,  C07C215/00 ,  C08L79/02 ,  C08L67/04 ,  C07C229/00 ,  C07C69/732 ,  C07C1/00

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US06465590B1

公开(公告)日：2002-10-15

申请号：US09271348

申请日：1999-03-17

申请人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

发明人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

IPC分类号： C08F1226

CPC分类号： C08G61/08 ,  C08F2/38 ,  C08F36/20 ,  C08F290/06 ,  C08F290/14 ,  C08G59/00 ,  C08L19/006 ,  C08L53/02 ,  C08F4/26 ,  C08F4/80 ,  C08L2666/02 ,  C08L2666/14

摘要： The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl. In another aspect of the invention, methods for controlling the molecular weight of the resulting telechelic polymer are also presented.

摘要翻译： 本发明涉及具有下式的可交联端基的遥爪聚合物及其制备方法，其中n为整数;是二甲苯基; Y为烷基; Z为可交联端基。 一般来说，本发明的合成方法包括在糠醛的钌或锇催化剂的存在下使具有可交联端的官能化链转移剂与环烯反应：M是钌或锇; X和X1独立地为任何阴离子配体; L和L1 是任何中性电子给体配体; R和R 1各自是氢或取代或未取代的取代基，其中取代基选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯 C 1 -C 20烷氧基，C 2 -C 20烷氧基，C 2 -C 20炔氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基和C 1 -C 20烷基亚磺酰基。 在本发明的另一方面，还提供了用于控制所得遥爪聚合物的分子量的方法。

公开(公告)号：US07745652B2

公开(公告)日：2010-06-29

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C07C51/43

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20080103346A1

公开(公告)日：2008-05-01

申请号：US11665723

申请日：2005-10-14

申请人： Kenneth A. Burdett ,  Baymond M. Collins ,  Bob R. Maughon ,  Michael L. Tulchinsky

发明人： Kenneth A. Burdett ,  Baymond M. Collins ,  Bob R. Maughon ,  Michael L. Tulchinsky

IPC分类号： C07C7/144

CPC分类号： C07C7/144 ,  B01D61/027 ,  C07C6/04 ,  C07C2531/24

摘要： A process for separating a homogeneous metathesis catalyst and, optionally, one or more homogeneous metathesis catalyst degradation products from a metathesis reaction mixture containing in addition to said metathesis catalyst and said metathesis catalyst degradation product(s), one or more olefin metathesis products, one or more unconverted reactant olefins, and optionally, a solvent. The process involves contacting the metathesis reaction mixture with a nanofiltration membrane, such as a polyimide nanofiltration membrane, so as to recover a permeate containing a substantial portion of the olefin reaction products, the unconverted reactant olefins, and optional solvent, and a retentate containing the metathesis catalyst, and optionally, metathesis catalyst degradation product(s). In another aspect, this invention pertains to a continuous metathesis reaction-catalyst separation process, preferably, conducted in a nanofiltration membrane reactor.

摘要翻译： 一种用于从包含所述复分解催化剂和所述复分解催化剂分解产物的复分解反应混合物中分离均相复分解催化剂和任选的一种或多种均化复分解催化剂降解产物的方法，一种或多种烯烃复分解产物，一种 或更多未转化的反应物烯烃，以及任选的溶剂。 该方法包括使复分解反应混合物与纳滤膜如聚酰亚胺纳滤膜接触，以回收含有大部分烯烃反应产物，未转化反应物烯烃和任选溶剂的渗透物，以及含有 复分解催化剂和任选的复分解催化剂降解产物。 另一方面，本发明涉及连续复分解反应 - 催化剂分离方法，优选在纳滤膜反应器中进行。

公开(公告)号：US07022789B2

公开(公告)日：2006-04-04

申请号：US11064033

申请日：2005-02-22

申请人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

发明人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

IPC分类号： C08F12/26 ,  C08F20/68

CPC分类号： C08G61/08 ,  C08F2/38 ,  C08F36/20 ,  C08F290/06 ,  C08F290/14 ,  C08G59/00 ,  C08L19/006 ,  C08L53/02 ,  C08F4/26 ,  C08F4/80 ,  C08L2666/02 ,  C08L2666/14

摘要： The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1–C20 alkyl, C2–C20 alkenyl, C2–C20 alkynyl, aryl, C1–C20 carboxylate, C1–C20 alkoxy, C1–C20 alkenyloxy, C2–C20 alkynyloxy, aryloxy, C2–C20 alkoxycarbonyl, C1–C20 alkylthio, C1–C20 alkylsulfonyl and C1–C20 alkylsulfinyl. In another aspect of the invention, methods for controlling the molecular weight of the resulting telechelic polymer are also presented.

公开(公告)号：US06867274B2

公开(公告)日：2005-03-15

申请号：US10151757

申请日：2002-05-21

申请人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

发明人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

IPC分类号： C08F4/70 ,  C08F36/20 ,  C08F12/26 ,  C08F4/44 ,  C08F20/68 ,  C08F20/70

CPC分类号： C08G61/08 ,  C08F2/38 ,  C08F36/20 ,  C08F290/06 ,  C08F290/14 ,  C08G59/00 ,  C08L19/006 ,  C08L53/02 ,  C08F4/26 ,  C08F4/80 ,  C08L2666/02 ,  C08L2666/14

摘要： The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C1-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl. In another aspect of the invention, methods for controlling the molecular weight of the resulting telechelic polymer are also presented.

摘要翻译： 本发明涉及具有下式的可交联端基的遥爪聚合物及其制备方法，其中n为整数;是二甲苯基; Y为烷基; Z为可交联端基。 一般来说，本发明的合成方法包括在糠醛的钌或锇催化剂的存在下使具有可交联端的官能化链转移剂与环烯反应：M是钌或锇; X和X 1独立地是任何阴离子配体; L和L 1是任何中性电子给体配体; R和R 1各自是氢或取代或未取代的取代基，其中取代基选自C1-C20烷基，C2-C20烯基，C1- C20炔基，芳基，C1-C20羧酸酯，C1-C20烷氧基，C2-C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基。 在本发明的另一方面，还提供了用于控制所得遥爪聚合物的分子量的方法。