There is provided a double-face driving silent chain wherein the size of each inner link plate of an exterior driving link train to a back face thereof is set to be equal to or greater than the size of each link plate of an interior driving link train. Thereby, inner side planes of the back face of the inner link plate abut against the both side planes of an interior driving sprocket and guide and prevent the silent chain from engaging with the sprocket in twist. All the link plates, other than the inner link plates of the exterior driving link train, have the same shape when seen from the side and the outermost link plate of the interior driving link train is thin as compared to the other link plates.