发明授权
- 专利标题: Methods for producing acetic acid
- 专利标题(中): 生产乙酸的方法
-
申请号: US10567900申请日: 2005-12-19
-
公开(公告)号: US07683212B2公开(公告)日: 2010-03-23
- 发明人: Hidetaka Kojima , Hiroyuki Miura
- 申请人: Hidetaka Kojima , Hiroyuki Miura
- 申请人地址: JP Sakai-Shi
- 专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人地址: JP Sakai-Shi
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: JP2004-377223 20041227
- 国际申请: PCT/JP2005/023268 WO 20051219
- 国际公布: WO2006/070632 WO 20060706
- 主分类号: C07C51/12
- IPC分类号: C07C51/12
摘要:
A method produces acetic acid by continuously reacting methanol with carbon monoxide in the presence of a rhodium catalyst, an iodide salt, methyl iodide, methyl acetate, and water; and thereby producing acetic acid at a production rate of 11 mol/L·hr or more while keeping the acetaldehyde content of a reaction mixture to 500 ppm or less, in which the reaction is carried out at a carbon monoxide partial pressure in a gaseous phase of a reactor of 1.05 MPa or more and/or at a methyl acetate content of the reaction mixture of 2 percent by weight or more to thereby keep the production rate of acetaldehyde to 1/1500 or less that of acetic acid. This method can reduce production of by-products without reducing the reaction rate of acetic acid even at a low water content and a low hydrogen partial pressure in a reaction system.
公开/授权文献
- US20070093676A1 Methods for producing acetic acid 公开/授权日:2007-04-26
信息查询