发明授权
- 专利标题: Platinum/ruthenium catalyst for direct methanol fuel cells
- 专利标题(中): 用于直接甲醇燃料电池的铂/钌催化剂
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申请号: US11573936申请日: 2005-08-13
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公开(公告)号: US07776781B2公开(公告)日: 2010-08-17
- 发明人: Marco Lopez , Peter Biberbach
- 申请人: Marco Lopez , Peter Biberbach
- 申请人地址: DE Hanau-Wolfgang
- 专利权人: Umicore AG & Co. KG
- 当前专利权人: Umicore AG & Co. KG
- 当前专利权人地址: DE Hanau-Wolfgang
- 代理机构: Smith, Gambrell & Russell, LLP
- 优先权: EP04019813 20040820
- 国际申请: PCT/EP2005/008827 WO 20050813
- 国际公布: WO2006/018257 WO 20060223
- 主分类号: B01J21/18
- IPC分类号: B01J21/18 ; B01J23/40 ; B01J23/74 ; B01J23/00 ; B01J23/42 ; B01J23/44 ; H01M4/02 ; H01M4/58 ; C22C5/04
摘要:
The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m2/g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane-electrode units containing the catalyst according to the invention having a high precious metal loading have an electrode layer thickness of less than 80 μm at a PtRu loading per unit area of the electrode of from 6 to 12 mg of PtRu/cm2 and lead to improved electric power in direct methanol fuel cells.
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